55525-94-5Relevant articles and documents
Novel [4 + 2] cycloaddition reaction of aryl-methylidenemalononitriles to unsaturated chalcogen amides. Synthesis, structure, and properties of triethylammonium 3,5,5-tricyano-1,4,5,6-tetrahydropyridine-2-selenolates and -thiolates
Frolov,Dotsenko,Krivokolysko,Kostyrko
, p. 1289 - 1300 (2013)
Reaction of arylmethylidenemalononitriles with 3-aryl-2-cyanoprop-2- eneselenoamides in the presence of Et3N gave triethylammonium 4,6-diaryl-3,5,5-tricyano-1,4,5,6-tetrahydropyridine-2-selenolates. A similar reaction with cyclohexylidenecyanothioacetamide yields triethylammonium 4-aryl-1,5,5-tri-cyano-3-azaspiro[5.5]undec-1-ene-2-thiolate. Alkylation of the obtained selenolates and thiolates gives 6-(alkylseleno)-2,4-diaryl-1,4- dihydropyridine-3,3,5(2H)-tricarbonitriles and 4-(alkylthio)-2-aryl-3-aza- spiro[5.5]undec-4-ene-1,1,5-tricarbonitriles, respectivelly. The structure of 2,4-di(2-furyl)-6-{[2-(4-methylphenyl)-2-oxoethyl]seleno}-1,4-dihydropyridine-3, 3,5(2H)-tricarbonitrile has been confirmed by the X-ray structural analysis.
Novel Synthesis of Indans, Tetralones, Condensed Benzocarbocyclic Nitriles and Condensed Pyridine-2(1H)-thiones from the Reactions of Cycloalkylidenemalononitriles with Arylmethylene(cyano)-acetamide and -thioacetamide
Elgemeie, Galal Eldin Hamza,Elzanate, Ali M.,Mansour, Abdel Kader
, p. 1073 - 1074 (2007/10/02)
A novel synthesis of indans, tetralons, condensed benzocarbocyclic nitriles and condensed pyridine-2(1H)-thiones from cycloalkylidenemalononitrile and arylmethylene(cyano)-acetamide and -thioacetamide is described.
Azo dyestuffs from benzene diazo component fused to an aliphatic ring and containing two cyano substituents ortho to the azo group
-
, (2008/06/13)
Azo dyestuffs of the formula STR1 wherein X1 and X2 denote alkyl, cycloalkyl, aralkyl or aryl or conjointly form the remaining members of a fused non-aromatic carbocyclic ring system, X3 denotes hydrogen, alkyl, aralkyl or aryl and K represents the radical of a coupling component as well as their preparation and use for dyeing and printing synthetic fibre materials.