55544-26-8Relevant academic research and scientific papers
Intermediacy of surface silylene in the direct synthesis of methylchlorosilanes
Okamoto, Masaki,Onodera, Satoshi,Okano, Tomoki,Suzuki, Eiichi,Ono, Yoshio
, p. 67 - 71 (1997)
The reaction of silicon with methyl chloride was carried out in the presence of butadiene. The products consisted of 1,1-dichlorosila-cyclopent-3-ene, 1-methyl-1-chlorosilacyclopent-3-ene and 1-chlorosilacyclopent-3-ene besides methylchlorosilanes. Silacyclopent-3-enes accounted for 25% of the whole products. The high selectivity for silacyclopent-3-enes indicates that surface silylene is the intermediate in the reaction of silicon with methyl chloride.
