Journal of Organometallic Chemistry p. 67 - 71 (1997)
Update date:2022-08-04
Topics:
Okamoto, Masaki
Onodera, Satoshi
Okano, Tomoki
Suzuki, Eiichi
Ono, Yoshio
The reaction of silicon with methyl chloride was carried out in the presence of butadiene. The products consisted of 1,1-dichlorosila-cyclopent-3-ene, 1-methyl-1-chlorosilacyclopent-3-ene and 1-chlorosilacyclopent-3-ene besides methylchlorosilanes. Silacyclopent-3-enes accounted for 25% of the whole products. The high selectivity for silacyclopent-3-enes indicates that surface silylene is the intermediate in the reaction of silicon with methyl chloride.
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