556-70-7Relevant academic research and scientific papers
Kinetics of the condensation of oligosiloxanes containing acetoxyl and hydroxyl end groups catalyzed by uncharged nucleophiles in an acid-base inert solvent
Cypryk, M.,Rubinsztajn, S.,Chojnowski, J.
, p. 197 - 204 (2007/10/02)
Condensation of undecamethylpentasiloxane-1-ol (1) with 1-acetoxypentamethyldisiloxane (2) in methylene chloride in the presence of uncharged bases has been studied as a model for the coupling of acetoxyl and hydroxyl ended polydimethylsiloxane chains.Triethylamine acts not only as the acceptor of the acid released in the process but also as a Broensted base catalyst activating silanol group.However, weakly basic but strongly nucleophilic N-heterocycles such as 4-dimethylaminopyridine are more effective catalysts promoting the condensation by acting as nucleophiles to activate the acetoxysilane.
