55800-31-2Relevant academic research and scientific papers
Iron-Catalyzed α-Alkylation of Ketones with Secondary Alcohols: Access to β-Disubstituted Carbonyl Compounds
Bettoni, Léo,Gaillard, Sylvain,Renaud, Jean-Luc
supporting information, (2020/03/13)
An iron-catalyzed borrowing hydrogen strategy has been applied in the synthesis of β-branched carbonyl compounds. Various secondary benzylic and aliphatic alcohols have been used as alkylating reagents under mild reaction conditions. The ketones have been
CONJUGATE ADDITION OF GRIGNARD REAGENTS TO UNSATURATED KETONES: GC/MS-HPLC STUDY. ISOLATION AND OXIDATION OF E AND Z ENOLS OF A KETONE
Pinkus, A. G.,Logaraj, S.
, p. 6801 - 6806 (2007/10/02)
The conjugate addition of phenylmagnesium bromide to benzalacetomesitylene (1) was studied.The only product resulting from 1,4-addition was Kohler's ketone (4) in 84+/-1 percent yield based on (1) by isolation and analysis.The byproducts from 4 were forme
