56077-92-0

Basic information

• Product Name: Methyl,dioxy-
• CAS NO: 56077-92-0
• Molecular Weight: 46.0257
• Mol File: 56077-92-0.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Methyl,dioxy- (CAS DataBase Reference)
• NIST Chemistry Reference: Methyl,dioxy- (56077-92-0)
• EPA Substance Registry System: Methyl,dioxy- (56077-92-0)

Safety Data

• Hazardous Substances Data: 56077-92-0(Hazardous Substances Data)

Upstream product

• 14840-85-8 dihydroxymethyl radical 
• 1195-32-0 1-methyl-4-isopropenylbenzene 
• 25163-88-6 2-(4-tert-butylphenyl)propene 
• 1712-71-6 3-chloro-α-methylstyrene 
• 74-85-1 ethene 
• 1712-69-2 1-isopropenyl-4-methoxybenzene 
• 350-40-3 2-(4-fluorophenyl)-1-propene 
• 1830-68-8 1-isopropenyl-4-nitro-benzene 
• 1712-70-5 1-chloro-4-(1-methylethenyl)-benzene 
• 109-53-5 isobutyl vinyl ether 

Downstream Products

• 700-58-3 2-Adamantanone 
• 128649-03-6 C₁₁H₁₆O₂S 
• 128649-04-7 homothiaadamantanone 
• 64-18-6 formic acid 
• 50-00-0 formaldehyd 

Relevant articles and documents

Production of the radicals in the ozonolysis of ethene: A chamber study by FT-IR and PERCA

The ozonolysis of ethene in dry synthetic air at atmospheric pressure and room temperature (298 ± 2) K was investigated in a 6065-L reaction chamber by in situ analysis of stable species by FTIR and of total peroxy radicals PO2 (PO2 = HO2 + RO2) by a chemical amplifier instrument. The yields of radical production were determined based on steady state concentrations of the peroxy radicals and the partitioning between HO2 and RO2 derived from model simulations. The radical yield is 0.38 ± 0.02 for HO2 and 0.45 ± 0.03 for PO2.

Reaction of Carbonyl Oxides and Thioketones. Cycloaddition vs. Oxygen Atom Transfer

The ozonolysis of vinyl ethers (1a, b) in the presence of thioadamantan-2-one (4a) gave in each case the corresponding thio-ozonide (5a, b) in around 70percent yield, whilst ozonolysis of a mixture of vinyl ethers (1a-c) and thiobenzophenone derivatives (4b-d) gave the corresponding thione-S-oxides (8b-d) in 15-30percent yields, together with the benzophenones (6b-d).