56252-14-3Relevant academic research and scientific papers
Polyoxopalladate-Loaded Metal-Organic Framework (POP?MOF): Synthesis and Heterogeneous Catalysis
Ayass, Wassim W.,Balster, Torsten,Bhattacharya, Saurav,Hartwig, Andreas,Kortz, Ulrich,Nisar, Talha,Taffa, Dereje H.,Wagner, Veit,Wark, Michael
, (2020)
We report on the synthesis and characterization of the first polyoxo-noble-metalate-containing metal-organic framework (MOF) material, wherein the preformed MIL-101 has been impregnated with the discrete, cuboid-shaped polyoxopalladate [Pd13Se8O32]6- (Pd13Se8), leading to the composite Pd13Se8?MIL-101. This material was characterized by FTIR, TGA, elemental analysis, powder-XRD, N2 sorption (BET), SEM-EDX, and XPS. Furthermore, the Pd13Se8?MIL-101 composite was shown to be an effective, stable, and recyclable heterogeneous precatalyst for the Suzuki-Miyaura cross-coupling reaction at room temperature utilizing environmentally benign solvents, such as water and methanol.
Discovery of Polyoxo-Noble-Metalate-Based Metal-Organic Frameworks
Bhattacharya, Saurav,Ayass, Wassim W.,Taffa, Dereje H.,Schneemann, Andreas,Semrau, A. Lisa,Wannapaiboon, Suttipong,Altmann, Philipp J.,P?thig, Alexander,Nisar, Talha,Balster, Torsten,Burtch, Nicholas C.,Wagner, Veit,Fischer, Roland A.,Wark, Michael,Kortz, Ulrich
, p. 3385 - 3389 (2019)
Here we report on the synthesis, structure, and characterization of the first example of a polyoxopalladate (POP)-based metal-organic framework (MOF). This novel class of materials comprises discrete polyoxo-13-palladate(II) nanocubes [Pd13Osu
Synthesis of pentathiepanes and isolation of the conformers based on high inversion barrier of the pentathiepane ring
Sugihara, Yoshiaki,Takeda, Hitoshi,Nakayama, Juzo
, p. 597 - 605 (2007/10/03)
Acenaphtho[1,2-a]acenaphthylene (1) was sulfurated with elemental sulfur to give a pentathiepane derivative (2). A dynamic NMR spectrum analysis revealed that the two naphthalene rings of 2 are chemically nonequivalent up to 100 °C. The pentathiepane ring
