56368-47-9

Usage

InChI:InChI=1/C12H15NOS/c15-12(13-6-8-14-9-7-13)10-11-4-2-1-3-5-11/h1-5H,6-10H2

Upstream product

• 150-60-7 dibenzyl disulphide 
• 4394-85-8 4-morpholinecarboxaldehyde 
• 16601-01-7 benzenethiosulfonic acid S-benzyl ester 
• 103-34-4 4,4'-dithiodimorpholine 
• 201230-82-2 carbon monoxide 
• 100-39-0 benzyl bromide 
• 110-91-8 morpholine 
• 37734-45-5 benzyl chlorothioformate 

Downstream Products

• 57266-43-0 S,S-dioxo-Sλ⁶-morpholine-4-carbothioic acid S-benzyl ester 
• 57266-37-2 S-oxo-Sλ⁴-morpholine-4-carbothioic acid S-benzyl ester 

Relevant academic research and scientific papers

Visible-light-promoted synthesis of secondary and tertiary thiocarbamates from thiosulfonates andN-substituted formamides

A general visible-light-promoted metal-free synthesis of secondary and tertiary thiocarbamates starting from thiosulfonates andN-substituted formamides is developed. By employing rhodamine B as a photocatalyst andtert-butyl hydroperoxide (TBHP) as an oxidant, a wide scope of thiocarbamates can be obtained through direct thiolation of acyl C-H bonds under irradiation of blue light at room temperature for 12 h.

Reaction of Thiolates with Carbon Monoxide

Thiolates generated from elemental sulfur with amines or lithium amides, easily reacted with carbon monoxide to form thiocarbamates in good yields.Furthermore, the reaction of diaminodisulfide with carbon monoxide in the presence of DBU proceeded similarl