56504-12-2Relevant academic research and scientific papers
Palladium-catalyzed cross-coupling of aryl chlorides with arylsilatranes
Yamamoto, Yutaro,Baralle, Alexandre,Godefroy, Ana?s,Murakami, Kei,Yorimitsu, Hideki,Osuka, Atsuhiro
, p. 568 - 574 (2017)
The cross-coupling reactions of arylsilatranes with readily available and inexpensive aryl chlorides were carried out in toluene/THF at 100 °C for 3 h in the presence of tetrabutylammonium fluoride as an activator for smooth transmetalation and catalytic amounts of palladium(II) acetate and XPhos.
CARBON-SILICON BOND CLEAVAGE OF ORGANOTRIALKOXYSILANES AND ORGANOSILATRANES WITH m-CHLOROPERBENZOIC ACID AND N-BROMOSUCCINIMIDE. NEW ROUTE TO PHENOLS, PRIMARY ALCOHOLS AND BROMIDES
Hosomi, Akira,Iijima, Susumu,Sakurai, Hideki
, p. 243 - 246 (2007/10/02)
Alkyl- and aryltriethoxysilanes undergo oxidative carbon-silicon bond cleavage smoothly with m-chloroperbenzoic acid (MCPBA) to afford the corresponding alcohols.Silatranes similarly gave alcohols and bromides with MCPBA and N-bromosuccinimide, respectively.
