5651-33-2

Upstream product

• 63045-46-5 tert-butylperoxy 2-(methylthio)benzoate 
• 79894-26-1 N-Benzoyloxy-N-tert-butyl-2-methylsulfanyl-benzamide 
• 79894-28-3 N-tert-Butyl-2-methylsulfanyl-N-(4-nitro-benzoyloxy)-benzamide 
• 79894-32-9 N-t-butyl-2-(benzoyloxymethylthio)benzamide 

Downstream Products

• 77586-91-5 2,2'-dithiobis(2,6-dimethylbenzanilide) 
• 3724-10-5 2-(methylthio)benzoic acid 
• 4892-02-8 Methyl thiosalicylate 
• 119-80-2 2,2'-dithiobenzoic acid 
• 5054-53-5 benzo[1,2]dithiol-3-ylidene-phenyl-amine 
• 2514-36-5 2-benzylbenzo[d]isothiazol-3(2H)-one 

Relevant academic research and scientific papers

SULFURANYL RADICAL STRUCTURE AND REACTIONS OF o-(THIO)BENZOYLOXYL RADICALS FORMED BY THE DECOMPOSITION OF t-BUTYL o-(THIO)-PERBENZOATES STUDIED BY 1H AND 13C CIDNP AND 17O NMR.

**1H and **1**3C CIDNP signals were observed in the methyl group of o-(methylthio)benzoic acid and the methylene group of 3,1-benzoxathian-4-one during the thermal decomposition of t-butyl o-(methylthio)perbenzoate. The results show that the free 'o-(methylthio)benzoyloxyl radical' itself is better represented as the bridged sulfuranyl radical in which most of the spin density is localized at the sulfur atom rather than in the carboxyl. Thermolysis of t-butyl o-(methylthio)- and o-(phenylthio)perbenzoates-carbonyl-**1**7O was carried out and the oxygen labels were detected by **1**7O NMR spectroscopy. The migration of phenyl group and the peroxomonosulfate oxidation of o-(phenylthio)benzoic acid are also discussed.

The Thermal Decomposition of N,O-Diacyl-N-t-butylhydroxylamines. II. Thermal Rearrangement of O-Acyl-N--N-t-butylhydroxylamines

Several O-acyl-N--N-t-butylhydroxylamines (1) were prepared and their thermal decompositions were studied.The thermal decomposition of 1 at 200 deg C in o-dichlorobenzene gave N-t-butyl-2-(acyloxymethylthio)benzamide (4), the carboxylic acid derived from the acyl part of 1, and 2-t-butyl-1,2-benzothiazol-3(2H)-one as the main products, together with small amounts of 4H-3,1-benzoxathiin-4-one, N-t-butyl-2-(methylthio)benzamide, methyl ester of the carboxylic acid, and N-t-butylamide.The benzamide (4) was found to be an initial product of the thermolysis and the subsequent decomposition gave the carboxylic acid and other products.Pummerer type reaction, via acylaminosulfonium ion as the intermediate, was suggested for the thermal decomposition of 1 since similar products were also obtained by the Pummerer reaction of N-t-butyl-2-(methylsulfinyl)benzamide with acylating reagents.