566912-07-0

Upstream product

• 100-84-5 1-methoxy-3-methyl-benzene 
• 19614-12-1 2-bromo-5-methoxybenzyl bromide 
• 82192-57-2 triisopropyl(prop-1-ynyl)silane 

Downstream Products

• 566912-10-5 methyl 3-[4-(triisopropylsilyl)-3-butynyl]-4-({2-[4-(triisopropylsilyl)-3-butynyl]-1-naphthyl}ethynyl)phenyl ether 
• 566912-22-9 3-hexahelicenyl(diphenyl)phosphine oxide 
• 566912-20-7 N-(diphenylmethylene)-3-hexahelicenamine 
• 566912-26-3 2-(6-hepten-3-ynyl)-1-{[2-(6-hepten-3-ynyl)-4-methoxyphenyl]ethynyl}naphthalene 
• 566912-11-6 2-(3-butynyl)-1-{[2-(3-butynyl)-4-methoxyphenyl]ethynyl}naphthalene 
• 503272-79-5 4-iodo-3-[4-(triisopropylsilyl)-3-butynyl]phenyl methyl ether 

Relevant academic research and scientific papers

Synthesis of 3-hexahelicenol and its transformation to 3-hexahelicenylamines, diphenylphosphine, methyl carboxylate, and dimethylthiocarbamate

A nonphotochemical synthetic route to 3-hexahelicenol is reported. It involves a key [2+2+2] cycloisomerization of CH3O-substituted triyne that is readily available from 1-methoxy-3-methylbenzene and 1-bromo-2-(bromomethyl)naphthalene. Further