566912-26-3

Upstream product

• 106-95-6 allyl bromide 
• 566912-11-6 2-(3-butynyl)-1-{[2-(3-butynyl)-4-methoxyphenyl]ethynyl}naphthalene 
• 37763-43-2 1-bromo-2-(bromomethyl)naphthalene 
• 19614-12-1 2-bromo-5-methoxybenzyl bromide 
• 100-84-5 1-methoxy-3-methyl-benzene 
• 566912-10-5 methyl 3-[4-(triisopropylsilyl)-3-butynyl]-4-({2-[4-(triisopropylsilyl)-3-butynyl]-1-naphthyl}ethynyl)phenyl ether 
• 566912-09-2 [4-(1-ethynylnaphthalen-2-yl)but-1-yn-1-yl][tri(propan-2-yl)]silane 
• 223596-91-6 1-Iodo-2-[4-(triisopropylsilyl)but-3-yn-1-yl]naphthalene 
• 223596-90-5 [4-(1-bromo-2-naphthyl)-1-butynyl](triisopropyl)silane 
• 566912-07-0 4-bromo-3-[4-(triisopropylsilyl)-3-butynyl]phenyl methyl ether 
• 503272-79-5 4-iodo-3-[4-(triisopropylsilyl)-3-butynyl]phenyl methyl ether 
• 566912-08-1 triisopropyl(4-{1-[(trimethylsilyl)ethynyl]-2-naphthyl}-1-butynyl)silane 

Relevant academic research and scientific papers

Synthesis of 3-hexahelicenol and its transformation to 3-hexahelicenylamines, diphenylphosphine, methyl carboxylate, and dimethylthiocarbamate

A nonphotochemical synthetic route to 3-hexahelicenol is reported. It involves a key [2+2+2] cycloisomerization of CH3O-substituted triyne that is readily available from 1-methoxy-3-methylbenzene and 1-bromo-2-(bromomethyl)naphthalene. Further