56717-64-7

Basic information

• Product Name: pentafluorophenyl-cyclohexyl thioether
• Synonyms: pentafluorophenyl-cyclohexyl thioether
• CAS NO: 56717-64-7
• Molecular Weight: 282.277
• Mol File: 56717-64-7.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: pentafluorophenyl-cyclohexyl thioether(CAS DataBase Reference)
• NIST Chemistry Reference: pentafluorophenyl-cyclohexyl thioether(56717-64-7)
• EPA Substance Registry System: pentafluorophenyl-cyclohexyl thioether(56717-64-7)

Safety Data

• Hazardous Substances Data: 56717-64-7(Hazardous Substances Data)

Upstream product

• 421-17-0 Trifluoromethylsulfenyl chloride 
• 110-82-7 cyclohexane 
• 14999-80-5 trifluoromethyl pentafluorophenyl disulfide 
• 1494-06-0 bis(pentafluorophenyl) disulfide 
• 372-64-5 Bis(trifluoromethyl)disulfid 
• 27918-31-6 pentafluorobenzenesulfenyl chloride 
• 662-42-0 heptafluoro-propane-1-sulphenic acid chloride 
• 70168-12-6 pentafluorophenyl-prop-2-enyl thioether 
• 771-62-0 pentafluorophenylthiol 
• 110-83-8 cyclohexene 
• 4837-39-2 S-cyclohexyl cyclohexane-1-sulfonothioate 
• 1206-46-8 trimethyl(pentafluorophenyl)silane 
• 51098-05-6 Methyl-dithiocarbamic acid pentafluorophenyl ester 
• 344-07-0 1-chloro-2,3,4,5,6-pentafluorobenzene 

Relevant articles and documents

The organocatalytic synthesis of perfluorophenylsulfides: Via the thiolation of trimethyl(perfluorophenyl)silanes and thiosulfonates

The organic superbase t-Bu-P4-catalyzed direct thiolation of trimethyl(perfluorophenyl)silanes and thiosulfonates was developed. Yields of perfluorophenylsulfides of up to 97% under catalysis of 5 mol% t-Bu-P4 were achieved. This method was shown to provide an efficient way to construct the perfluorophenyl-sulfur bond under mild metal-free reaction conditions. This journal is

EVIDENCE FOR INTRAMOLECULAR CYCLOADDITION PROCESS IN THE PHOTO-CLAISEN REARRANGEMENT

Photoreaction of pentafluorophenyl-prop-2-enyl ether in cyclohexane at λ=253.7 nm resulted in intramolecular cycloaddition, forming 2,3,4,5,6-pentafluoro-1,8-epoximethano bicycloocta-2,4-diene, while a similar reaction of the thio analogue led to C - S bond cleavage.