5675-01-4

Upstream product

• 110-82-7 cyclohexane 
• 931-51-1 cyclohexylmagnesiumchloride 
• 4837-38-1 cyclohexanesulfonyl chloride 
• 7446-70-0 aluminium trichloride 
• 74829-95-1 sodium cyclohexane sulfinate 
• 931-50-0 cyclohexylmagnesium bromide 
• 860427-46-9 cyclohexanesulfonyl-succinic acid 

Downstream Products

• 4837-39-2 S-cyclohexyl cyclohexane-1-sulfonothioate 
• 6922-46-9 cyclohexanesulfonic acid 
• 860427-46-9 cyclohexanesulfonyl-succinic acid 
• 52962-89-7 N-cyclohexanesulfonyl-N,N'-bis-(morpholine-4-carbonyl)-hydrazine 
• 4830-63-1 2-Hydroxy-2-cyclohexylfonyl-1-phenyl-aethanon-⁽¹⁾ 
• 42604-85-3 (1-Cyclohexanesulfonyl-2-nitro-ethyl)-benzene 
• 42604-87-5 3-(cyclohexylsulfonyl)-1,3-diphenylpropan-1-one 
• 42604-99-9 (E)-5-Cyclohexanesulfonyl-1,5-diphenyl-pent-1-en-3-one 
• 4830-66-4 2-Hydroxy-2--1-cyclohexyl-aethan-on-(1) 
• 77391-58-3 3-(cyclohexylsulfonyl)-1-phenylpyrrolidine-2,5-dione 

Relevant academic research and scientific papers

Direct Substitution of Secondary and Tertiary Alcohols to Generate Sulfones under Catalyst- and Additive-Free Conditions

An environmentally benign protocol that affords propargylic sulfones containing highly congested carbon centers from easily accessible alcohols and sulfinic acids with water as the only byproduct is reported. The reaction proceeded via an in situ dehydrative cross-coupling process by taking advantage of the synergetic actions of multiple hydrogen bonds rather than relying on an external catalyst and/or additives to achieve high product distribution.

Mercury-Photosensitized Sulfination, Hydrosulfination, and Carbonylation of Hydrocarbons: Alkane and Alkene Conversion to Sulfonic Acids, Ketones, and Aldehydes

Mercury-photosensitized sulfination of alkanes, RH, with SO2 forms sulfinic acids (RSOOH) and sulfinate esters (RSOOR) in high conversion and yield; oxidation of the mixture produces RSO2OH in high yield.Mercury-photosensitized hydrosulfination of alkenes with H2 and SO2 gives RSO2OH after oxidative workup.Mercury-photosensitized carbonylation of alkanes with CO gives RCHO and R2CO.