56757-75-6Relevant academic research and scientific papers
Multiblock copolymer synthesis via controlled radical polymerization in aqueous dispersions. Part 1: Synthesis of S-tert-alkyl-N,N- alkoxycarbonylalkyldithiocarbamates
Bussels, Raf,Koning, Cor E.
, p. 1167 - 1174 (2007/10/03)
In a novel two- or three-step synthetic route, S-(1,4-phenylenebis(propane- 2,2-diyl)) bis(N-methyldithiocarbamate) is reacted at low temperature with various alkyl chloroformates to form various S-tert-alkyl-N,N- alkoxycarbonylmethyl-dithiocarbamate RAFT
MULTIFUNCTIONAL AND BIFUNCTIONAL DITHIOCARBOXYLATE COMPOUNDS, MONOFUNCTIONAL ALKOXYCARBONYL DITHIOCARBAMATE COMPOUND, A METHOD FOR THE PREPARATION OF ALKOXYCARBONYL DITHIOCARBAMATE COMPOUNDS AS WELL AS A METHOD FOR THE PREPARATION OF MULTIBLOCK COPOLYMERS BY MEANS OF RADICAL POLYMERISATION
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Page/Page column 25, (2010/02/13)
The present invention relates to a multifunctional dithiocarboxylate compound. The present invention furthermore relates to a bifunctional dithiocarboxylate compound. The present invention also relates to a monofunctional alkoxycarbonyl dithiocarbamate compound. The present invention further relates to a method for the synthesis of alkoxycarbonyl dithiocarbamate compounds. In addition, the present invention relates to a method for the preparation of one or more polymers by means of a radical polymerisation process, using a monofunctional, a bifunctional or a multifunctional dithiocarboxylate compound.
A safe and efficient procedure to prepare alkyl and alkoxyalkyl chlorides and dichlorides by catalytic decomposition of the corresponding alkyl and alkoxyalkyl chloroformates and bischloroformates with hexabutylguanidinium chloride
Violleau,Thiebaud,Borredon,Le Gars
, p. 367 - 373 (2007/10/03)
Small amounts of hexabutylguanidinium chloride (0.01 mol%) decomposes pure chloroformates or bischloroformates with different lengths of carbon chains by a semicontinuous process to diminish run-away risk, leading to chloride compounds with high yield and purity.
Oxyformamidates
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, (2008/06/13)
Compounds of the formula STR1 WHEREIN A is a linking group, X is an O--CO-- or --SO2 -- group and n is at least 2, are prepared from the corresponding N',N'-disubstituted hydrazides by quaternization and treatment with alkali or reaction with an alkylene epoxide or from the corresponding compound wherein n = 1 and A is a polymerizable group by polymerization. The compounds are unstable to heat and may be used as cross-linking agents for polymers or as chain-extending agents, bonding agents or adhesives.
