56845-76-2Relevant academic research and scientific papers
Small-scale one-pot reductive alkylation of unprotected aminocyclitols with supported reagents
Sisa, Miroslav,Trapero, Ana,Llebaria, Amadeu,Delgado, Antonio
experimental part, p. 3167 - 3170 (2009/04/07)
A protocol for the reductive alkylation of unprotected aminocyclitols with supported reagents and scavengers is described. The method is operatively simple and provides the corresponding secondary amines in high yields and purities. Georg Thieme Verlag Stuttgart.
Stereoselective synthesis of several azido/amino- and diazido/diamino-myo-inositols and their phosphates from p-benzoquinone
Podeschwa, Michael A.L.,Plettenburg, Oliver,Altenbach, Hans-Josef
, p. 1919 - 1929 (2007/10/03)
A practical route is described for the preparation of azido-myo-inositols, amino-myo-inositols and azido-conduritol B derivatives. Starting from p-benzoquinone, optically pure compounds in both forms can be prepared via enzymatic resolution of a derived diacetoxy conduritol B derivative. Selective introduction of nitrogen-containing functional groups in four of the six possible positions in the cyclitol moiety is followed by further functionalization to yield the target compounds.
