56865-66-8Relevant academic research and scientific papers
Access to functionalized imidazolidin-2-one derivatives by Iron-catalyzed oxyamination of alkenes
Manick, Anne-Doriane,Aubert, Sidonie,Yalcouye, Boubacar,Prangé, Thierry,Berhal, Farouk,Prestat, Guillaume
supporting information, p. 11485 - 11492 (2018/10/20)
Functionalized imidazolidin-2-one were prepared by using an iron-catalyzed alkene oxyamination reaction. Hy-droxylamine derivatives were used in this atom-economical process, and the addition of an external oxidant was not required. The conditions developed were shown to be efficient for mono-, di-, and trisubstituted double bonds, and a large scope of diamino alcohol precursors were delivered in good yields with good diastereoselectivities. The mechanistic pathway was studied and appears to involve both a fused aziridine and a carbocationic species.
2,4-Dinitrophenylhydroxylamine: An efficient and more general reagent for iron-catalyzed allylic amination
Singh,Nicholas
, p. 3087 - 3097 (2007/10/03)
2,4-Dinitrophenylhydroxylamine (1) is an efficient reagent for the iron-catalyzed regioselective allylic amination of olefins. Moderate to excellent yields of N-DNP-N-allyl amines (2) are obtained resulting from introduction of the N-DNP group at the less
