36043-44-4

Basic information

• Product Name: Benzene, (1,2-dibromo-1-methylethyl)-
• CAS NO: 36043-44-4
• Molecular Formula: C9H10Br2
• Molecular Weight: 277.986
• Mol File: 36043-44-4.mol
• Article Data: 22

Chemical Properties

• CAS DataBase Reference: Benzene, (1,2-dibromo-1-methylethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, (1,2-dibromo-1-methylethyl)-(36043-44-4)
• EPA Substance Registry System: Benzene, (1,2-dibromo-1-methylethyl)-(36043-44-4)

Safety Data

• Hazardous Substances Data: 36043-44-4(Hazardous Substances Data)

Upstream product

• 98-82-8 Isopropylbenzene 
• 75-09-2 dichloromethane 
• 7726-95-6 bromine 
• 98-83-9 isopropenylbenzene 
• 3575-19-7 2-bromo-2-phenylpropane 

Downstream Products

• 4217-66-7 1,2-dihydroxy-2-phenylpropane 
• 98-83-9 isopropenylbenzene 
• 762-04-9 phosphonic acid diethyl ester 
• 7534-40-9 2-phenylallyl acetate 
• 128318-85-4 1-(1-azidoprop-2-en-2-yl)benzene 
• 3360-54-1 3-bromo-2-phenylprop-1-ene 
• 16917-35-4 (E)-(1-bromoprop-1-en-2-yl)benzene 
• 31778-29-7 1-bromo-2-phenylpropan-2-ol 
• 56865-66-8 N-methyl-2-phenylallylamine 
• 22500-26-1 N,N-diethyl-2-phenylprop-2-en-1-amine 

Relevant articles and documents

Preparation method of 1-aryl-1,2-dibromoethane

The invention relates to a preparation method of 1-aryl-1,2-dibromoethane. The preparation method of 1-aryl-1,2-dibromoethane includes the steps: under a nitrogen atmosphere, a solvent, an aryl alkaneand N-bromosuccinimide are added in to a reaction tube in sequence, a dibromination reaction is conducted at 80-120 DEG C for 12-48 hours, then, the dibromination reaction is finished, the solvent isremoved through evaporation, and through column chromatography separation, 1-aryl-1,2-dibromoethane compounds are obtained. According to the preparation method of 1-aryl-1,2-dibromoethane, a synthesis technology is simple, reaction conditions are mild, the yield of 1-aryl-1,2-dibromoethane is high, and thus the preparation method of 1-aryl-1,2-dibromoethane is easy to industrialize.

Practical regio- and stereoselective azidation and amination of terminal alkenes

There is significant interest in developing more rapid and efficient production of nitrogen-containing allylic compounds, as widely used in various syntheses. This work reports a variety of allylic azides and allylic amines synthesized by an efficient, new one-pot protocol that employs readily available terminal alkenes as starting materials. This method is highly regio- and stereoselective, affording the linear (E)-isomer, under metal-free conditions. This process tolerates several functional groups including halogen-containing molecules; it is general for azides and amine nucleophiles; and, adducts were obtained in good yields.

Efficient bromination of olefins, alkynes, and ketones with dimethyl sulfoxide and hydrobromic acid

The oxidative bromination of olefins, alkynes, and ketones has been developed with HBr as the brominating reagent and DMSO as the mild oxidant. The simple conditions, high bromide-atom-economy, as well as easy accessibility and low cost of DMSO and HBr make the present strategy prospective for the synthesis of dibrominated alkanes, dibrominated alkenes and α-bromoketones.