56865-85-1Relevant academic research and scientific papers
Pyrazole and benzothiazole palladacycles: Stable and efficient catalysts for carbon-carbon bond formation
Gai,Grigg,Ramzan,Sridharan,Collard,Muir
, p. 2053 - 2054 (2000)
Cyclopalladated phosphine free pyrazole complexes 1 and benzothiazole complexes 2 are excellent catalysts for the Heck vinylation of aryl iodides and termolecular queuing cascades, leading to turnover numbers of > 106 in some cases, at moderate
Copper-Catalyzed Decarboxylative Functionalization of Conjugated β, Γ-Unsaturated Carboxylic Acids
Zhang, Wei,Wang, Chengming,Wang, Qiu
, p. 13179 - 13185 (2020/11/17)
Copper-catalyzed decarboxylative coupling reactions of conjugated β,γ-unsaturated carboxylic acids have been achieved for allylic amination, alkylation, sulfonylation, and phosphinoylation. This approach was effective for a broad scope of amino, alkyl, su
Copper(II) catalyzed allylic amination of terpenic chlorides in water
Boualy, Brahim,Harrad, Mohamed Anouar,El Houssame, Soufiane,El Firdoussi, Larbi,Ali, Mustapha Ait,Karim, Abdallah
experimental part, p. 46 - 50 (2012/04/10)
A highly efficient method for the synthesis of allylic amines from terpenic chlorides by cheap copper (II) as catalyst in water has been developed. Allylic chlorides react with high regioselectivity in the presence of secondary amines, under mild conditions to give N-allylic amines in excellent yields.
Stannylated allyl carbonates as versatile building blocks for the diversity oriented synthesis of allylic amines and amides
Bukovec, Christian,Kazmaier, Uli
supporting information; experimental part, p. 2743 - 2750 (2011/05/04)
Stannylated allylic carbonates are suitable substrates for Pd-catalyzed allylic aminations. In DMF and with [allylPdCl]2 as catalyst the stannylated allyl amines formed can be directly coupled with electrophiles according to the Stille protocol, giving rise to highly functionalized buiding blocks in excellent yields.
8-Methylquinoline palladacycles: Stable and efficient catalysts for carbon-carbon bond formation
Evans, Paul,Hogg, Paul,Grigg, Ronald,Nurnabi, Mohamed,Hinsley, Joanne,Sridharan, Visuvanathar,Suganthan, Selvaratnam,Korn, Stewart,Collard, Simon,Muir, Jane E.
, p. 9696 - 9704 (2007/10/03)
Cyclopalladated, phosphine free, 8-methyl quinoline based complexes (2a-j) are excellent catalysts for the Heck vinylation of aryl iodides and bromides with turnover numbers of greater than 25 million observed in some cases. The catalysts are air and moisture stable.
