5765-65-1

Basic information

• Product Name: BENZOIC ACID MORPHOLIN-4-YL ESTER
• Synonyms: BENZOIC ACID MORPHOLIN-4-YL ESTER
• CAS NO: 5765-65-1
• Molecular Formula: C₁₁H₁₃NO₃
• Molecular Weight: 207.22582
• Mol File: 5765-65-1.mol
• Article Data: 45

Chemical Properties

• Melting Point: 83 °C(Solv: cyclohexane (110-82-7))
• Boiling Point: 314.3±52.0 °C(Predicted)
• Appearance: /
• Density: 1.22±0.1 g/cm3(Predicted)
• PKA: -2.50±0.20(Predicted)
• CAS DataBase Reference: BENZOIC ACID MORPHOLIN-4-YL ESTER(CAS DataBase Reference)
• NIST Chemistry Reference: BENZOIC ACID MORPHOLIN-4-YL ESTER(5765-65-1)
• EPA Substance Registry System: BENZOIC ACID MORPHOLIN-4-YL ESTER(5765-65-1)

Safety Data

• Hazardous Substances Data: 5765-65-1(Hazardous Substances Data)

Usage

Uses

Benzoic acid morpholin-4-yl ester is a useful research chemical.

Upstream product

• 98-88-4 benzoyl chloride 
• 5765-63-9 4-hydroxymorpholine 
• 65-85-0 benzoic acid 
• 110-91-8 morpholine 
• 94-36-0 dibenzoyl peroxide 

Downstream Products

• 92-53-5 4-Phenylmorpholine 
• 7178-40-7 N-(o-tolyl)morpholine 
• 10316-00-4 4-benzyl-morpholine 
• 27347-14-4 N-(4-methoxyphenyl)morpholine 
• 39242-76-7 4-(2,4-dinitrophenyl)morpholine 
• 70291-67-7 N-(4-chlorophenyl)morpholine 
• 4280-40-4 4-(4-fluorophenyl)morpholine 
• 98223-72-4 N-(1-naphthyl)morpholine 
• 10282-31-2 4-morpholinobenzonitrile 
• 5320-98-9 N-(2-nitrophenyl)morpholine 
• 189065-49-4 4-(3-(trifluoromethyl)phenyl)morpholine 
• 19614-15-4 4-(morpholin-4-yl)benzoic acid ethyl ester 
• 132993-25-0 trifluoromethanesulfonic acid 4-(morpholin-4-yl)phenyl ester 
• 113845-69-5 4-(4-trifluoromethylphenyl)morpholine 

Relevant articles and documents

Copper-Catalyzed Aminoarylation of Alkenes via Aminyl Radical Addition and Aryl Migration

We describe a new strategy for aminoarylation of alkenes by copper-catalyzed smiles rearrangement using O-benzoylhydroxylamines as the amine reagent. This method affords various β-amino amide derivatives possessing a quaternary carbon center with wide functional group tolerance and high regioselectivity. The mechanistic studies indicate that the transformation can involve aminyl radical intermediates under acid-free condition.

External-oxidant-free amino-benzoyloxylation of unactivated alkenes of unsaturated ketoximes with: O -benzoylhydroxylamines

A new copper-catalyzed two-component amino-benzoyloxylation of unactivated alkenes of unsaturated ketoximes with O-benzoylhydroxylamines as the benzoyloxy sources is developed. Chemoselectivity of this method toward amino-benzoyloxylation or oxy-benzoyloxylation of alkenyl ketoximes relies on the position of the tethered olefins, and provides an external-oxidant-free alkene difunctionalization route that directly utilizes O-benzoylhydroxylamines as the benzoyloxy radical precursors and internal oxidants for the divergent synthesis of cyclic nitrones and isoxazolines.

An unprecedented cobalt-catalyzed selective aroylation of primary amines with aroyl peroxides

A novel and facile cobalt-catalyzed selective aroylation of primary amines with aroyl peroxides was developed for the synthesis of aryl amides. It was unprecedented that C[sbnd]N bond formation product was selectively generated without the common N[sbnd]O bond formation product. Aroyl peroxides act as the sole aroylation reagent without additional base or oxidant. The reactions proceeded under mild conditions and showed broad substrates scope with a series of primary amines and aroyl peroxides.