57082-90-3

Upstream product

• 35466-83-2 allyl methyl carbonate 
• 5451-55-8 4-tert-butylcyclohexanecarboxylic acid 
• 191613-96-4 (4-tert-Butylcyclohexyl)acetic acid methyl ester 
• 20667-19-0 methyltriphenylphosphonium iodide 
• 88166-21-6 (4-tert-butyl-1-cyclohexyl)acetaldehyde 
• 7080-86-6 1-(tert-butyl)-4-bromocyclohexane 
• 24850-33-7 allyltributylstanane 

Downstream Products

• 88166-22-7 3-(4-tert-Butyl-cyclohexyl)-propionaldehyde 
• 88166-23-8 4-(4-tert-Butyl-cyclohexyl)-butan-2-ol 

Relevant academic research and scientific papers

Organophotoredox/palladium dual catalytic decarboxylative Csp3-Csp3coupling of carboxylic acids and π-electrophiles

A dual catalytic decarboxylative allylation and benzylation method for the construction of new C(sp3)-C(sp3) bonds between readily available carboxylic acids and functionally diverse carbonate electrophiles has been developed. The new process is mild, operationally simple, and has greatly improved upon the efficiency and generality of previous methodology. In addition, new insights into the reaction mechanism have been realized and provide further understanding of the harnessed reactivity.

127. Conformationally Controlled Odor Perception in 'Steroid-type' Scent Molecules

A series of compounds possessing a 'steroid-type' scent and related to 4-(4'-t-butylcyclohexyl)-4-methyl-2-pentanones (1 and 2) have been synthesized.The odor of these compounds has been found to be dependent on their conformation; only when the molecule can assume a steroid-like shape there is an interaction with the odor chemoreceptor.