57098-50-7Relevant academic research and scientific papers
Homolytic addition of bromine-containing addends to cyclohexene
Vasil'eva, T. T.,Mysov, E. I.,Terent'ev, A. B.
, p. 2062 - 2064 (2007/10/02)
The addition of XBr (X = CCl3, CHBr2, CH2CO2Me, or PhCH2) to cyclohexene in the presence of benzoyl peroxide (BP) or Fe(CO)5 + DMF was studied.In the presence of BP, a product of the addition of the Br and PhCO2 radicals is formed along with the expected adduct.The content of the former increases as the efficiency of XBr as the carrier of the chain reaction decreases. - Key words: radicals; addition; cyclohexene; bromotrichloromethane; bromoform; methyl bromoacetate; benzyl bromide; metallocomplex initiation.
