57204-66-7Relevant academic research and scientific papers
Tandem IBX-Promoted Primary Alcohol Oxidation/Opening of Intermediate β,γ-Diolcarbonate Aldehydes to (E)-γ-Hydroxy-α,β-enals
Kumari, Anupama,Gholap, Sachin P.,Fernandes, Rodney A.
, p. 2278 - 2290 (2019/06/17)
A tandem IBX-promoted oxidation of primary alcohol to aldehyde and opening of intermediate β,γ-diolcarbonate aldehyde to (E)-γ-hydroxy-α,β-enal has been developed. Remarkably, the carbonate opening delivered exclusively (E)-olefin and no over-oxidation of γ-hydroxy was observed. The method developed has been extended to complete the stereoselective total synthesis of both (S)- and (R)-coriolides and d-xylo- and d-arabino-C-20 guggultetrols.
Efficient Stereocontrol in the Sigmatropic Rearrangement of Allylic Sulfoxides
Sato, Tsuneo,Otera, Junzo,Nozaki, Hitosi
, p. 2779 - 2780 (2007/10/02)
The sigmatropic rearrangement of allylic sulfoxides occurs with an extremely high E preference when a substituent branched at the β position of a sulfinyl group is involved.
