5739-81-1Relevant academic research and scientific papers
Stereoselective addition of alcohol to acetylenecarboxylate catalyzed by silver(I) salt
Kataoka, Yasutaka,Matsumoto, Osamu,Tani, Kazuhide
, p. 727 - 728 (1996)
A silver(I) salt catalyzed the stereoselective trans addition of alcohol to dimethyl acetylenedicarboxylate smoothly under mild conditions to afford dimethyl methoxyfumarate in a quantitative yield.
Nucleophilic attack of 2-sulfinyl acrylates: A mild and general approach to sulfenic acid anions
Singh, Suneel P.,O'Donnell, Jennifer S.,Schwan, Adrian L.
experimental part, p. 1712 - 1717 (2010/07/04)
An increasing number of reactions of sulfenic acid anions are being demonstrated in the literature. As such, mild, general and reliable means for the generation of sulfenates are due. In the current paper, an addition/elimination of 2-sulfinyl acrylates using various nucleophiles is demonstrated and evaluated as a protocol for alkane- and arenesulfenate generation. Cyclohexanethiolate, methoxide and n-butyllithum each exhibit some merit for the reaction, and the thiolate is established as a mild, selective and effective reagent to release sulfenates from 2-sulfinyl acrylates. The stereospecificity of the addition/elimination of each nucleophile is recognized, and an explanation for the specificity is offered for thiolate and methoxide.
