57526-47-3

Basic information

• Product Name: 3,7,7-trimethylbicyclo[4.1.0]heptane-3,4-diol
• Synonyms: 3,7,7-trimethylbicyclo[4.1.0]heptane-3,4-diol;3,4-Caranediol;Einecs 260-788-9
• CAS NO: 57526-47-3
• Molecular Formula: C₁₀H₁₈O₂
• Molecular Weight: 170.24872
• EINECS: 260-788-9
• Mol File: 57526-47-3.mol
• Article Data: 12

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 3,7,7-trimethylbicyclo[4.1.0]heptane-3,4-diol(CAS DataBase Reference)
• NIST Chemistry Reference: 3,7,7-trimethylbicyclo[4.1.0]heptane-3,4-diol(57526-47-3)
• EPA Substance Registry System: 3,7,7-trimethylbicyclo[4.1.0]heptane-3,4-diol(57526-47-3)

Safety Data

• Hazardous Substances Data: 57526-47-3(Hazardous Substances Data)

Usage

InChI:InChI=1/C10H18O2/c1-9(2)6-4-8(11)10(3,12)5-7(6)9/h6-8,11-12H,4-5H2,1-3H3

Upstream product

• 79-21-0 peracetic acid 
• 498-15-7 (+)-Δ³-carene 
• 64-19-7 acetic acid 
• 7722-84-1 dihydrogen peroxide 
• 13466-78-9 3-carene 
• 20296-50-8 δ-3-carene 
• 936-92-5 (1S,3R,4S,6R)-3,4-epoxy-3,7,7-trimethylbicyclo[4.1.0]heptane 
• 936-91-4 α-3,4-Epoxycarane 
• 936-91-4 (1S,3R,4S,6R)-3,4-epoxycarane 
• 2225-98-1 3,4-epoxycarane 
• 936-91-4 3-carene epoxide 

Downstream Products

• 99-87-6 4-methylisopropylbenzene 
• 58930-63-5 (3¹R,3³S)-3²,3²-dimethyl-3(1,3)cyclopropyla-5-oxohexanoic acid 
• 24348-06-9 (+)-3β-hydroxy-4-caranone 
• 936-92-5 (1S,3R,4S,6R)-3,4-epoxy-3,7,7-trimethylbicyclo[4.1.0]heptane 
• 36482-69-6 (1R,4S,6S)-4-hydroxy-4,7,7-trimethylbicyclo[4.1.0]heptan-3-one 
• 10395-46-7 (+)-3α,4β-caranediol 
• 33116-78-8 (1S,3R)-(+)-3-hydroxy-4-isocaranyl tosylate 
• 22556-08-7 trans-3,4-caranediol 

Relevant articles and documents

Acidic three-liquid-phase microemulsion systems based on balanced catalytic surfactant for epoxidation and sulfide oxidation under mild conditions

Didecyldimethylammonium tungstate has been designed as a balanced catalytic surfactant to form acidic three-liquid-phase microemulsion systems at room temperature in the presence of water, a non-chlorinated solvent and dimethyldioctylammonium salts (hydrogen sulfate and dihydrogen phosphate). The triphasic system is efficient for the oxidation of olefins, sulfides and thiophenes under mild conditions. Moreover, the recovery and reusability of the catalyst, the straightforward separation of products and catalysts in two distinct phases as well as the possible use of environmentally friendly solvents such as tert-butyl acetate, make this system particularly attractive for catalytic oxidation reactions involving hydrogen peroxide as the primary oxidant under acidic or neutral conditions.

Process for producing carbonyl or hydroxy compound

There are disclosed are a method for producing at least one compound selected from a carbonyl compound and a hydroxy adduct compound by an oxidative cleavage or addition reaction of an olefinic double bond of an olefin compound,???which contains??????reacting an olefin compound with hydrogen peroxide, utilizing as a catalyst, at least one member selected from(a) tungsten,(b) molybdenum, or(c) a tungsten or molybdenum metal compound containing(ia) tungsten or (ib) molybdenum and(ii) an element of Group IIIb, IVb, Vb or VIb excluding oxygen, anda catalyst composition.

Ring Opening of Epoxides with Sodium Azide in Water. a Regioselective pH-Controlled Reaction

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