57585-21-4Relevant articles and documents
Biotransformations of racemic 2,3-allenenitriles in biphasic systems: Synthesis and transformations of enantioenriched axially chiral 2,3-allenoic acids and their derivatives
Ao, Yu-Fei,Wang, De-Xian,Zhao, Liang,Wang, Mei-Xiang
, p. 3103 - 3110 (2014/05/06)
Catalyzed by Rhodococcus erythropolis AJ270 whole cells in an aqueous phosphate buffer-n-hexane biphasic system, racemic axially chiral 2,3-allenenitriles underwent hydrolysis to afford enantioenriched (aR)-2,3-allenamides and (aS)-2,3-allenoic acids with