56618-58-7Relevant articles and documents
(3S,8E)-1,3-Dihydroxy-8-decen-5-one, a Metabolite of Streptomyces fimbriatus
Keller-Schierlein, Walter,Wuthier, Damian,Drautz, Hannelore
, p. 1253 - 1261 (1983)
From the cultures of Streptomyces fimbriatus, strain Tue 2335, the title compound 1 was isolated by solvent extraction, chromatography, and distillation.Its constitution was determined by spectroscopic investigations of 1 and some of its derivatives, and the chirality by transformation to (R)-1,3-isopropylidenedioxydecane (12); a reference sample of the latter was prepared from (R)-methyl 3-hydroxydecanoate (10).In the equilibrium mixture the keto form 1 predominates the two hemiacetals 2a and 2b.Compound 1 is inactive against bacteria, yeasts and fungi.
Total Synthesis and Stereochemical Assignment of Sunshinamide and Its Anticancer Activity
Goswami, Rajib Kumar,Mondal, Joyanta,Sarkar, Ruma,Sen, Prosenjit
, (2020/02/15)
Total synthesis of cyclodepsipeptide sunshinamide has been achieved for the first time using a convergent approach. The key features of this synthesis comprise Crimmins acetate aldol, Shiina esterification, amide coupling, macrolactamization, and an Isub
Synthesis and Characterization of Four Diastereomers of Monorhamnolipids
Palos Pacheco, Ricardo,Eismin, Ryan J.,Coss, Clifford S.,Wang, Hui,Maier, Raina M.,Polt, Robin,Pemberton, Jeanne E.
, p. 5125 - 5132 (2017/05/04)
Rhamnolipids are amphiphilic glycolipids biosynthesized by bacteria that, due to their low toxicity and biodegradability, are potential replacements for synthetic surfactants. The previously limited access to pure materials at the gram scale has hindered
