582322-05-2

Upstream product

• 604-69-3 β-D-glucose pentaacetate 
• 28244-94-2 p-tolyl-2,3,4,6-tetra-O-acetyl-1-thio-β-D-glucopyranoside 
• 106-45-6 para-thiocresol 
• 1152-39-2 p-methylphenyl 1-thio-β-D-glucopyranoside 
• 100-39-0 benzyl bromide 
• 582322-04-1 4-methylphenyl (S)-4,6-O-[(4-methoxyphenyl)methylene]-1-thio-β-D-glucopyranoside 

Downstream Products

• 582322-07-4 6-O-[(4-methoxyphenyl)methyl]-2,3-bis-O-(phenylmethyl)-D-glucopyranose-1-acetate 
• 582322-06-3 4-methylphenyl (S)-6-O-[(4-methoxyphenyl)methyl]-2,3-bis-O-(phenylmethyl)-1-thio-β-D-glucopyranoside 

Relevant academic research and scientific papers

Synthesis of aminocyclohexitol via carbon-carbon bond-forming radical cyclization of oxime ether.

The stannyl radical mediated-cyclization of oxime ether, derived from D-glucose, gave the aminocyclohexitol derivative. Stereoselective C-C bond forming cyclization proceeded via favorable conformers minimizing A(1,3)-strain between the oxime ether group and alpha-substituents.