582322-05-2Relevant articles and documents
Synthesis of aminocyclohexitol via carbon-carbon bond-forming radical cyclization of oxime ether.
Miyabe, Hideto,Nishiki, Akiyoshi,Naito, Takeaki
, p. 100 - 103 (2007/10/03)
The stannyl radical mediated-cyclization of oxime ether, derived from D-glucose, gave the aminocyclohexitol derivative. Stereoselective C-C bond forming cyclization proceeded via favorable conformers minimizing A(1,3)-strain between the oxime ether group and alpha-substituents.