583027-80-9

Basic information

• Product Name: Benzenesulfonamide, N-(2-acetylphenyl)-4-methyl-N-2-propenyl-
• CAS NO: 583027-80-9
• Molecular Formula: C18H19NO3S
• Molecular Weight: 329.42
• Mol File: 583027-80-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzenesulfonamide, N-(2-acetylphenyl)-4-methyl-N-2-propenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenesulfonamide, N-(2-acetylphenyl)-4-methyl-N-2-propenyl-(583027-80-9)
• EPA Substance Registry System: Benzenesulfonamide, N-(2-acetylphenyl)-4-methyl-N-2-propenyl-(583027-80-9)

Safety Data

• Hazardous Substances Data: 583027-80-9(Hazardous Substances Data)

Upstream product

• 98-59-9 p-toluenesulfonyl chloride 
• 551-93-9 2-aminoacetophenone 
• 1859-70-7 N-(2-acetylphenyl)-4-methylbenzenesulfonamide 
• 106-95-6 allyl bromide 
• 80217-67-0 1-(2-(allylamino)phenyl)ethanone 

Downstream Products

• 402823-03-4 N-allyl-N-p-toluenesulfonyl-2-(1-methoxyvinyl)aniline 
• 675578-67-3 N-allyl-N-p-toluenesulfonyl-2-(1,1-dimethoxyethyl)aniline 
• 402823-05-6 N-allyl-N-p-toluenesulfonyl-2-[1-(t-butyldimethylsilyloxy)vinyl]aniline 
• 583027-88-7 phosphoric acid 1-{2-[allyl-(toluene-4-sulfonyl)-amino]-phenyl}-vinyl ester diethyl ester 

Relevant articles and documents

Cyanative alkene-aldehyde coupling: Ni(0)-NHC-Et2AlCN mediated chromanol synthesis with high cis-selectivity at room temperature

Described are several classes of Ni(0) mediated cyanative alkene-aldehyde coupling reactions, providing 6-membered cores, which complement existing cyclization technology in several respects. Et2AlCN was used as both a cyclization accelerator and CN source. The NHC ligand may have a positive effect in differentiating reductive elimination and syn-β-hydride elimination.

A convenient approach to cyclic enol phosphates via ring-closing metathesis

A strategy employing the second generation Grubbs catalyst in order to facilitate the generation of a variety of cyclic enol phosphates, including 2H-chromen-4-yl, 1,2-dihydroquinolin-4-yl, 2H-thiochromen-4-yl, 2H-thiochromen-4-yl 1,1-dioxide, and benzofu