58345-96-3

Basic information

• Product Name: Tetramethylammonium bicarbonate
• Synonyms: Tetramethylammonium bicarbonate;Tetramethylammonium hydrogencarbonate
• CAS NO: 58345-96-3
• Molecular Formula: CHO₃*C₄H₁₂N
• Molecular Weight: 135.16162
• Mol File: 58345-96-3.mol
• Article Data: 2

Chemical Properties

• Appearance: /
• Storage Temp.: Refrigerator
• Solubility: Chloroform, Water
• CAS DataBase Reference: Tetramethylammonium bicarbonate(CAS DataBase Reference)
• NIST Chemistry Reference: Tetramethylammonium bicarbonate(58345-96-3)
• EPA Substance Registry System: Tetramethylammonium bicarbonate(58345-96-3)

Safety Data

• Hazardous Substances Data: 58345-96-3(Hazardous Substances Data)

Usage

Uses

Tetramethylammonium bicarbonate (cas# 58345-96-3) is used in the method for preparing graphene with high purity and stable performance.

Upstream product

• 124-38-9 carbon dioxide 

Downstream Products

• 96-49-1 [1,3]-dioxolan-2-one 
• 4427-94-5 butylene carbonate 
• 75-59-2 tetramethyl ammoniumhydroxide 
• 19456-17-8 (4R,5R)-4,5-diphenyl-1,3-dioxolan-2-one 
• 1439-07-2 trans-Stilbene oxide 
• 4427-92-3 4-Phenyl-1,3-dioxolan-2-one 

Relevant articles and documents

Carboxylate-assisted formation of alkylcarbonate species from co 2 and tetramethylammonium salts with a β-amino acid anion

Tetramethylammonium-based molten salts bearing a β-amino acid anion (TMAAs) are synthesized through Michael addition reactions of amines with methyl acrylate followed by hydrolysis and subsequent neutralization by using aqueous tetramethylammonium hydroxide. The CO2 capture performances of the TMAAs are evaluated and are shown to interact with CO2 in a 1:1 mode in both water and alcohol. FTIR and 13C NMR spectroscopic studies on the interactions of TMAAs with CO2 indicate that the type of CO 2 adduct varies with the solvent used. When water is used as the solvent, a bicarbonate species is produced, whereas hydroxyethylcarbonate and methylcarbonate species are generated in ethylene glycol and methanol, respectively. Computational calculations show that the carboxylate groups of TMAAs contribute towards the formation and stabilization of 1:1 CO2 adducts through hydrogen bonding interactions with the hydrogen atoms of the amino groups.