58567-80-9

Basic information

• Product Name: Benzene, 1-(1,1-dimethylethyl)-4-propyl-
• Synonyms: 4-tert-butylpropylbenzene;1-tert-butyl-4-propyl-benzene;1-tert-Butyl-4-propyl-benzol;Benzene,1-(1,1-dimethylethyl)-4-propyl;p-t-butyl-n-propylbenzene
• CAS NO: 58567-80-9
• Molecular Formula: C13H20
• Molecular Weight: 176.302
• Mol File: 58567-80-9.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: Benzene, 1-(1,1-dimethylethyl)-4-propyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-(1,1-dimethylethyl)-4-propyl-(58567-80-9)
• EPA Substance Registry System: Benzene, 1-(1,1-dimethylethyl)-4-propyl-(58567-80-9)

Safety Data

• Hazardous Substances Data: 58567-80-9(Hazardous Substances Data)

Upstream product

• 98-51-1 4-tert-butyltoluene 
• 7252-86-0 4-tert-butylthioanisole 
• 920-39-8 isopropylmagnesium bromide 
• 74-85-1 ethene 
• 120-12-7 anthracene 
• 939-97-9 4-tert-Butylbenzaldehyde 
• 68175-34-8 1-(tert-butyl)-4-(prop-1-en-1-yl)benzene 
• 118334-80-8 N-acyloxyphthalimide 
• 75-66-1 2-methylpropan-2-thiol 
• 78-94-4 methyl vinyl ketone 
• 24475-36-3 4-[4-(1,1-dimethylethyl)phenyl]butanoic acid 
• 80-54-6 lilial 

Relevant articles and documents

Regioselective differentiation of vicinal methylene C-H bonds enabled by silver-catalysed nitrene transfer

Silver-catalyzed nitrene insertion enables the formation of benzosultams in good yield and with regioselectivity complementary to other transition metal nitrene-transfer catalysts. Preferential formation of six-membered benzosultam rings predominates for alkyl-substituted benzenesulphonamide precursors. Ligand-controlled tunability is also achieved for benzenesulphonamides with γ-branched alkyl substituents. Mechanistic probes suggest that the reaction pathway differs depending on whether a α (benzylic) or β (homobenzylic) C-H bond undergoes amidation, as well as the catalyst identity.

Reductive decarboxylation of N-(acyloxy)phthalimides via redox-initiated radical chain mechanism

Highly efficient reductive decarboxylation of N-(acyloxy)phthalimides which are readily prepared from carboxylic acids was achieved by visible light irradiation using Ru(bpy)3Cl2 as a sensitizer in the presence of BNAH and t-BuSH via radical chain mechanism.

PHOTODECARBOXYLATION OF UNMODIFIED CARBOXYLIC ACIDS WITH USE OF AZA AROMATIC COMPOUNDS

A very simple procedure for photodecarboxylation of intact carboxylic acids leading to alkanes is developed with use of aza aromatic compounds as light absorbers and t-BuSH as a hydrogen donor.