58587-04-5

Basic information

• Product Name: Cyclohexanecarbothioic acid, S-2-pyridinyl ester
• CAS NO: 58587-04-5
• Molecular Formula: C12H15NOS
• Molecular Weight: 221.323
• Mol File: 58587-04-5.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Cyclohexanecarbothioic acid, S-2-pyridinyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexanecarbothioic acid, S-2-pyridinyl ester(58587-04-5)
• EPA Substance Registry System: Cyclohexanecarbothioic acid, S-2-pyridinyl ester(58587-04-5)

Safety Data

• Hazardous Substances Data: 58587-04-5(Hazardous Substances Data)

Upstream product

• 2127-03-9 2,2'-dipyridyldisulphide 
• 98-89-5 Cyclohexanecarboxylic acid 
• 2637-34-5 2-Sulfanylpyridine 
• 2719-27-9 cyclohexanylcarbonyl chloride 
• 60718-45-8 1-cyclohexanecarbonyl-1H-imidazole 
• 25666-60-8 potassium 1-cyclohexyl methanoate 
• 128100-67-4 1,2-bis(1,1-dioxido-3-oxobenzo[d]isothiazol-2(3H)-yl)ethane-1,2-dione 

Downstream Products

• 75211-59-5 cyclohexyl-(1H-pyrrol-2-yl)methanone 
• 55409-09-1 1,2-dicyclohexyl-2-hydroxy-ethanone 
• 951-88-2 1,2-dicyclohexylethanedione 
• 110-83-8 cyclohexene 
• 7469-80-9 cyclohexyl 4-methoxyphenyl ketone 
• 85014-02-4 cyclohexyl-(4-fluoromethyl)methanone 
• 55268-74-1 2-cyclohexanecarbonyl-1,2,3,6,7,11b-hexahydro-pyrazino[2,1-a]isoquinolin-4-one 

Relevant articles and documents

Cobalt-catalyzed acylation-reactions of (hetero)arylzinc pivalates with thiopyridyl ester derivatives

A cobalt-catalyzed acylation reaction of various primary, secondary and tertiary alkyl, benzyl and (hetero)aryl S-pyridyl thioesters with (hetero)arylzinc pivalates is reported. The thioesters were prepared directly from the corresponding carboxylic acids under mild conditions, thus tolerating sensitive functional groups. Acylations of α-chiral S-pyridyl esters proceeded with very high stereoretention leading to optically enriched α-chiral ketones.

Convenient synthesis of amides, esters, and thioesters using 2,2'-oxalyldi(2,3-dihydro-3-oxobenzisosulfonazole)

-

Synthesis of Thiol Esters by Carboxylic Trichlorobenzoic Anhydrides

Thiocarboxylic S-esters were obtained rapidly and in high yields by treating the mixed anhydrides prepared from 2,4,6-trichlorobenzoyl chloride and carboxylic acid, with various types of thiols in the presence of 4-dimethylaminopyridine.