58656-97-6Relevant articles and documents
A Cyanide-Free Synthesis of Acylcyanides through Ru-Catalyzed C(sp3)-H-Oxidation of Benzylic Nitriles
Eisele, Pascal,Bauder, Michael,Hsu, Shih-Fan,Plietker, Bernd
, p. 689 - 691 (2019/05/07)
A practical method for generation of acylcyanides devoid of any external cyanide sources is presented that relies on a mild Ru-catalyzed selective C?H-oxidation of benzylic nitriles. The starting materials are smoothly generated through condensation of the corresponding carboxylic acid amides using silanes. The obtained acylcyanides can be employed in a plethora of transformation as exemplified to some larger extend in the sequence of C?H-oxidation-Tischenko-rearrangement for the generation of structurally diverse benzoyloxycyanohydrines.
Transition-metal-free alkoxycarbonylation of aryl halides
Zhang, Hua,Shi, Renyi,Ding, Anxing,Lu, Lijun,Chen, Borui,Lei, Aiwen
supporting information, p. 12542 - 12545 (2013/02/23)
Transitions: The title reaction has been developed for the synthesis of a variety of tert-butyl benzoates by employing 1,10-phenanthroline as an additive. Various functional groups were tolerated and heteroaryl iodides were also suitable substrates. Preli
1,2-dioxetane derivatives, intermediates for syntheses thereof and methods of producing the intermediates
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, (2008/06/13)
A chemiluminescent 1,2-dioxetane derivative having a formula (I): STR1 wherein R1 and R4 each represent, individually, hydrogen, an alkyl group, an alkoxyl group, a hydroxyl group, or --OSi(R9 R10 R11) in which R9, R10 and R11 each represent an alkyl group; R2, R3, R5 and R6 each represent, individually, hydrogen or an alkyl group, provided that R2, R3, R5 and R6 each cannot be hydrogen at the same time, and that R2 and R3, and R5 and R6, each taken together, can form a cycloalkyl group; R7 represents an alkyl group; R8 represents hydrogen, an alkoxyl group, a phosphate salt group, or --OSi(R9 R10 R11); intermediates for synthesizing the above 1,2-dioxetane derivative; and methods of producing the intermediates are provided.