5876-90-4

Basic information

• Product Name: 2-benzyl-1-[(4-methoxyphenyl)amino]-3-methylpyrido[1,2-a]benzimidazole-4-carbonitrile
• Synonyms: 2-Benzyl-1-[(4-methoxyphenyl)amino]-3-methylpyrido[1,2-a]benzimidazole-4-carbonitrile; Pyrido[1,2-a]benzimidazole-4-carbonitrile, 1-[(4-methoxyphenyl)amino]-3-methyl-2-(phenylmethyl)-
• CAS NO: 5876-90-4
• Molecular Formula: C₉H₁₀Br₂O₃
• Molecular Weight: 418.4898
• Mol File: 5876-90-4.mol
• Article Data: 19

Chemical Properties

• Density: 1.2g/cm³
• Refractive Index: 1.656
• CAS DataBase Reference: 2-benzyl-1-[(4-methoxyphenyl)amino]-3-methylpyrido[1,2-a]benzimidazole-4-carbonitrile(CAS DataBase Reference)
• NIST Chemistry Reference: 2-benzyl-1-[(4-methoxyphenyl)amino]-3-methylpyrido[1,2-a]benzimidazole-4-carbonitrile(5876-90-4)
• EPA Substance Registry System: 2-benzyl-1-[(4-methoxyphenyl)amino]-3-methylpyrido[1,2-a]benzimidazole-4-carbonitrile(5876-90-4)

Safety Data

• Hazardous Substances Data: 5876-90-4(Hazardous Substances Data)

Upstream product

• 621-23-8 1,2,3-trimethoxybenzene 
• 7726-95-6 bromine 
• 570-02-5 2,4,6-trimethoxybenzoic acid 
• 830-79-5 2,4,6-trimethoxybenzaldehyde 
• 871893-76-4 2,4,6-trimethoxy-isophthalic acid 
• 10035-10-6 hydrogen bromide 
• 64-19-7 acetic acid 
• 832-58-6 1-(2,4,6-trimethoxyphenyl)ethanone 
• 186581-53-3 diazomethane 
• 84743-75-9 2,4-dibromo-1,3,5-trihydroxybenzene 
• 106-42-3 para-xylene 

Downstream Products

• 621-23-8 1,2,3-trimethoxybenzene 
• 60077-70-5 1,3-dibromo-5-(2,3-dibromo-4,5-dimethoxybenzyl)-2,4,6-trimethoxybenzene 
• 92670-03-6 2,4-bis(trimethylsilyl)-1,3,5-trimethoxybenzene 

Relevant articles and documents

HALOGENATED PHLOROGLUCINOLS FROM RHABDONIA VERTICILLATA

Six bromo- and/or chloro- derivatives of phloroglucinol have been obtained from the red alga Rhabdonia verticillata.Key Word Index - Rhamdonia verticillata; Rhambdoniaceae; halogenated phenols; bromo- and chlorophloroglucitols.

Oxidative bromination reactions in aqueous media by using Bu4NBr/TFA/H2O2 system

Metal-free oxidative bromination reactions in aqueous media were performed using tetrabutylammonium bromide, trifluoroacetic acid, and hydrogen peroxide under mild conditions. Oxidative bromination reaction of alkenes was found to afford the corresponding vic-bromides. Furthermore, this oxidative bromination system is applicable to the oxidative bromination of alkynes, arenes, and 3,4-dihydronaphthalen-1(2H)-one. A gram-scale bromination reaction was also performed successfully.

Cross-Dehydrogenative-Coupling of Alkoxybenzenes with Toluenes: Copper(II) Halide Mediated Tandem Halo/Benzylation of Arenes

A cross-dehydrogenative-coupling of alkoxybenzenes and toluenes with concomitant halogenation is reported. Conditions employed were the use of stoichiometric copper halide salts and dialkylperoxides to afford a range of bromoalkoxydi- and triarylmethanes. Preliminary mechanistic studies suggest that the in situ production of haloarenes (or dihaloarenes) followed by a copper-mediated coupling of a benzylic radical is operational.