58853-55-7

Basic information

• Product Name: 10-methoxybicyclo[4.4.1]undeca-1,3,5,7,9-pentaene
• Synonyms: 10-methoxybicyclo[4.4.1]undeca-1,3,5,7,9-pentaene
• CAS NO: 58853-55-7
• Molecular Formula: C₁₂H₁₂O
• Molecular Weight: 172.22
• Mol File: 58853-55-7.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 375.2°C at 760 mmHg
• Flash Point: 178.4°C
• Appearance: /
• Density: 1.06g/cm³
• Vapor Pressure: 1.71E-05mmHg at 25°C
• Refractive Index: 1.583
• CAS DataBase Reference: 10-methoxybicyclo[4.4.1]undeca-1,3,5,7,9-pentaene(CAS DataBase Reference)
• NIST Chemistry Reference: 10-methoxybicyclo[4.4.1]undeca-1,3,5,7,9-pentaene(58853-55-7)
• EPA Substance Registry System: 10-methoxybicyclo[4.4.1]undeca-1,3,5,7,9-pentaene(58853-55-7)

Safety Data

• Hazardous Substances Data: 58853-55-7(Hazardous Substances Data)

Usage

InChI:InChI=1/C12H12O/c1-13-12-8-4-6-10-5-2-3-7-11(12)9-10/h2-8H,9H2,1H3

Upstream product

• 2443-46-1 1,6-methano[10]annulene 
• 67-56-1 methanol 
• 15825-92-0 2-bromo-1,6-methano[10]annulene 
• 124-41-4 sodium methylate 

Downstream Products

• 133267-97-7 Bicyclo<4.4.1>undeca-3,6,8,10-tetraen-2,5-dion-2-(4-nitrophenyl)hydrazon 
• 89154-51-8 p-(5-Oxobicyclo(4.4.1)undeca-3,6,8,10-tetraen-2-yliden)hydrazinobenzoesaeureaethylester 
• 95122-44-4 C₂₂H₁₈N₄O 
• 95122-47-7 C₂₂H₁₈N₄O 
• 87399-28-8 Bicyclo<4.4.1>undeca-3,6,8,10-tetraen-2,5,dion-2-(2,4-dinitrophenylhydrazon) 
• 87399-26-6 Bicyclo<4.4.1>undeca-3,6,8,10-tetraen-2,5-dion-2-(4-methyl-2-nitrophenylhydrazon) 
• 87399-27-7 Bicyclo<4.4.1>undeca-3,6,8,10-tetraen-2,5-dion-2-(2-methyl-6-nitrophenylhydrazon) 
• 86226-28-0 5-[(4-Methoxy-2-nitro-phenyl)-hydrazono]-bicyclo[4.4.1]undeca-1⁽¹⁰⁾,3,6,8-tetraen-2-one 
• 86226-27-9 5-[(4-Chloro-2-nitro-phenyl)-hydrazono]-bicyclo[4.4.1]undeca-1⁽¹⁰⁾,3,6,8-tetraen-2-one 

Relevant articles and documents

Applications of MCD Spectroscopy: MO Ordering and Transannular Interaction in 1,6-Methanoannulenes from Analysis of Substituent Effects

Eight 2-substituted and nine 3-substituted 1,6-methanoannulenes have been synthesized, and their magnetic circular dichroism has been measured.The B terms of the Lb transition depend on the ?-electron effect of the substituent in a way which reveals the ordering of the four frontier molecular orbitals: a1, a2, b1, and b2 in the order of increasing energy.This result implies the presence of a strong transannular interaction between the bridgehead positions 1 and 6 on the bridged annulene ring.