59416-90-9

Upstream product

• 33658-48-9 2-methyl-1,7-heptanedioic acid dimethyl ester 
• 583-60-8 2-Methylcyclohexanone 
• 616-38-6 carbonic acid dimethyl ester 
• 66088-37-7 ethyl 1-methyl-2-oxocyclohexancarboxylate 
• 67-56-1 methanol 
• 64-19-7 acetic acid 
• 17640-15-2 methyl cyanoformate 
• 7500-91-6 methyl 2-methyl-1-oxocyclohexane-2-carboxylate 
• 186581-53-3 diazomethane 
• 52456-87-8 6-methyl-1-oxocyclohexane-2-carboxylic acid 
• 124-38-9 carbon dioxide 
• 19980-33-7 6-methyl-1-trimethylsiloxycyclohex-1-ene 

Downstream Products

• 84072-28-6 (+/-)-methyl 1,3-dimethyl-2-oxo-1-cyclohexanecarboxylate 
• 4884-89-3 <1,3-Dimethyl-1,3-dicarboxy-cyclohexyl-(2)-essigsaeure 
• 109040-12-2 (1,3-Dimethyl-3-methoxycarbonyl-cyclohexen-⁽¹⁾-yl)-essigsaeure 
• 100533-19-5 (1,3-Dimethyl-3-methoxycarbonyl-cyclohexen-⁽¹⁾-yl)-propionsaeure 
• 109400-50-2 (1,3-Dimethyl-3-methoxycarbonyl-cyclohexen-⁽¹⁾-yl)-essigsaeure-ethylester 
• 106591-27-9 (1,3-Dimethyl-3-methoxycarbonyl-cyclohexen-⁽¹⁾-yl)-propionsaeure-methylester 
• 142838-54-8 2,2-Bis-methoxycarbonylmethylsulfanyl-3-methyl-cyclohexanecarboxylic acid methyl ester 
• 142838-46-8 2,2-Bis-carboxymethylsulfanyl-3-methyl-cyclohexanecarboxylic acid methyl ester 

Relevant academic research and scientific papers

THRB RECEPTOR AGONIST COMPOUND AND PREPARATION METHOD AND USE THEREOF

The present invention discloses a compound represented by the following Formula (I) and a pharmaceutically acceptable salt thereof. The compound improves the THRα selectivity while maintaining good THRβ agonistic activity, thereby improving properties of

Efficient 1,3 ester shift in α-disubstituted β-ketoester enolates. Remarkable influence of the metal counterion on the rate of reaction

The efficient and rapid α to γ rearrangement of the carbalkoxy group in α-disubstituted β-ketoesters is reported. The reaction proceeds at room temperature and in high yields when performed under naked anion conditions. A crossover experiment using approp

A Short Synthesis of the 4-Demethoxy-11-deoxyanthracycline Skeleton. Regiospecific Enolate C-Carboxylation with Carbon Oxysulfide

Regiospecific C-carboxylation of enolate 2 and COS followed by methylation (CH3I) and cuprous triflate cyclization results in a tetracyclic product 9 which can be converted into 11-deoxyanthracyclines.

α-Carboxylation reaction of carbonyl compounds with bromomagnesium ureide-carbon dioxide adducts

Bromomagnesium ureide-carbon dioxide adducts, models of the carboxylated biotin complex, undergo caboxylation of a variety of carbonyl compounds in good yield.