594835-24-2Relevant academic research and scientific papers
Direct sulfonylation of Baylis-Hillman alcohols and diarylmethanols with TosMIC in ionic liquid-[Hmim]HSO4: An unexpected reaction
Garima,Srivastava, Vishnu P.,Yadav, Lal Dhar S.
experimental part, p. 4622 - 4626 (2011/09/21)
A Bronsted acidic ionic liquid-[Hmim]HSO4 promoted unexpected reaction of Baylis-Hillman alcohols and diarylmethanols with p-toluenesulfonylmethyl isocyanide (TosMIC) affording the corresponding sulfone derivatives instead of N-tosylmethyl amid
Synthesis of allyl aryl sulfone derivatives from Baylis-Hillman acetates in water
Karnakar, Konkala,Shankar, Jilla,Murthy, Sabbavarapu Narayana,Nageswar, Yadavalli Venkata Durga
experimental part, p. 875 - 880 (2011/06/27)
Various phenyl and p-tolyl allyl sulfone derivatives were prepared stereoselectively by reacting Baylis-Hillman acetates with sodium 4-R-benzenesulfinate (R=H, Me) in H2O. The reaction was very efficient in providing the corresponding sulfone d
An unexpected reaction of arenesulfonyl cyanides with allylic alcohols: Preparation of trisubstituted allyl sulfones
Reddy, Leleti Rajender,Hu, Bin,Prashad, Mahavir,Prasad, Kapa
experimental part, p. 172 - 174 (2009/04/10)
(Chemical Equation Presented) An efficient and practical protocol for the highly selective preparation of substituted allyl sulfones has been developed. Arenesulfonyl cyanides, Baylis-Hillman adducts, and simple allylic alcohols give an unforeseen outcome
