14897-67-7

Basic information

• Product Name: 1-Propanone, 2-nitro-1-phenyl-
• CAS NO: 14897-67-7
• Molecular Formula: C9H9NO3
• Molecular Weight: 179.175
• Mol File: 14897-67-7.mol
• Article Data: 17

Chemical Properties

• CAS DataBase Reference: 1-Propanone, 2-nitro-1-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Propanone, 2-nitro-1-phenyl-(14897-67-7)
• EPA Substance Registry System: 1-Propanone, 2-nitro-1-phenyl-(14897-67-7)

Safety Data

• Hazardous Substances Data: 14897-67-7(Hazardous Substances Data)

Upstream product

• 79-24-3 Nitroethane 
• 613-90-1 benzoyl cyanide 
• 75-65-0 tert-butyl alcohol 
• 705-60-2 1-phenyl-2-nitroprop-1-ene 
• 873-66-5 1-propenylbenzene 
• 509-14-8 tetranitromethane 
• 66323-99-7 trimethyl[(Z)-(1-phenyl-1-propenyl)oxy]silane 
• 10364-94-0 1-benzoylimidazole 
• 28735-55-9 lithium 1-nitroethan-1-ide 
• 93-55-0 1-phenyl-propan-1-one 
• 98-88-4 benzoyl chloride 
• 637-50-3 1-phenylpropene 
• 110621-89-1 3-phenyl-5-trinitromethyl-1,2,4-oxadiazole 
• 595-49-3 2,2-dinitropropane 

Downstream Products

• 5440-69-7 N-isopropylbenzamide 
• 100-51-6 benzyl alcohol 
• 93-55-0 1-phenyl-propan-1-one 
• 119-51-7 1-phenyl-1,2-propanedione 2-oxime 
• 26251-08-1 2-nitro-1-phenylpropan-1-ol 
• 17019-26-0 (E)-2-(hydroxyimino)-1-phenylpropan-1-one 
• 3480-59-9 (S)-N-(1-phenylethyl)benzamide 
• 579-07-7 1-Phenylpropane-1,2-dione 
• 1589528-90-4 (E)-5-(cyclohex-1-en-1-yl)-2-methyl-2-nitro-1-phenylpent-4-en-1-one 
• 1589528-89-1 (E)-2-(4-methyl-4-nitro-5-oxo-5-phenylpent-1-en-1-yl)cyclohex-1-en-1-yl acetate 
• 1589528-88-0 (E)-5-(2,7-di-tert-butyl-9,9-dimethyl-9H-xanthen-4-yl)-2-methyl-2-nitro-1-phenylpent-4-en-1-one 
• 1589528-87-9 (E)-5-(2,2-dimethyl-2H-chromen-6-yl)-2-methyl-2-nitro-1-phenylpent-4-en-1-one 

Relevant articles and documents

NO donors. Part 16: Investigations on structure-activity relationships of organic mononitrates reveal 2-nitrooxyethylammoniumnitrate as a high potent vasodilator

The vasoactive properties of 14 organic mononitrates were investigated in vitro using PGF2α-precontracted porcine pulmonary arteries. A surprisingly wide range of vasorelaxant potencies was observed (pD2: 3.36-7.50). Activities showed to be highly sensitive to the molecular structure and the substituents at the molecular carrier of the nitrate group. A correlation between lipophilicity and vasorelaxant potency could not be recognized. 2-Nitrooxyethylammoniumnitrate (1) was found to be slightly superior to the high potency trinitrate GTN.

Nitration of styrenes using 2-methyl-5-trinitromethyltetrazole

-

Convenient synthesis of 4,5-unsubstituted 3-aroylisoxazoles from methyl aryl ketones and (vinylsulfonyl)benzene in water

A convenient synthesis of 3-aroylisoxazoles from methyl ketones and (vinylsulfonyl)benzene in 2%TPGS-750-M/H2O has been developed. This reaction proceeds via tandem tert-butyl nitrite-promoted Csp3-H functionalization of methyl ketones, 1,3-dipolar cycloaddition and base-catalyzed aromatization, providing the corresponding products in moderate to good yields.