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1-Propanone, 2-nitro-1-phenyl- is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 14897-67-7 Structure
  • Basic information

    1. Product Name: 1-Propanone, 2-nitro-1-phenyl-
    2. Synonyms:
    3. CAS NO:14897-67-7
    4. Molecular Formula: C9H9NO3
    5. Molecular Weight: 179.175
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 14897-67-7.mol
  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: 1-Propanone, 2-nitro-1-phenyl-(CAS DataBase Reference)
    10. NIST Chemistry Reference: 1-Propanone, 2-nitro-1-phenyl-(14897-67-7)
    11. EPA Substance Registry System: 1-Propanone, 2-nitro-1-phenyl-(14897-67-7)
  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 14897-67-7(Hazardous Substances Data)

14897-67-7 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 14897-67-7 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,4,8,9 and 7 respectively; the second part has 2 digits, 6 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 14897-67:
(7*1)+(6*4)+(5*8)+(4*9)+(3*7)+(2*6)+(1*7)=147
147 % 10 = 7
So 14897-67-7 is a valid CAS Registry Number.

14897-67-7SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 16, 2017

Revision Date: Aug 16, 2017

1.Identification

1.1 GHS Product identifier

Product name 2-nitro-1-phenylpropan-1-one

1.2 Other means of identification

Product number -
Other names 2-methyl-2-nitro-1-phenyl-1-ethanone

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:14897-67-7 SDS

14897-67-7Relevant articles and documents

NO donors. Part 16: Investigations on structure-activity relationships of organic mononitrates reveal 2-nitrooxyethylammoniumnitrate as a high potent vasodilator

Koenig, Andreas,Roegler, Carolin,Lange, Kathrin,Daiber, Andreas,Glusa, Erika,Lehmann, Jochen

, p. 5881 - 5885 (2007)

The vasoactive properties of 14 organic mononitrates were investigated in vitro using PGF2α-precontracted porcine pulmonary arteries. A surprisingly wide range of vasorelaxant potencies was observed (pD2: 3.36-7.50). Activities showed to be highly sensitive to the molecular structure and the substituents at the molecular carrier of the nitrate group. A correlation between lipophilicity and vasorelaxant potency could not be recognized. 2-Nitrooxyethylammoniumnitrate (1) was found to be slightly superior to the high potency trinitrate GTN.

Facile Preparation of α-Nitroketones from Enol Silyl Ethers

Rathore, Rajendra,Lin, Zhe,Kochi, Jay K.

, p. 1859 - 1862 (1993)

Treatment of enol silyl ethers with the mild nitrating agent tetranitromethane gives good yields of α-nitroketones at room temperature and below.

Enantioselective Addition of α-Nitroesters to Alkynes

Davison, Ryan T.,Parker, Patrick D.,Hou, Xintong,Chung, Crystal P.,Augustine, Sara A.,Dong, Vy M.

supporting information, p. 4599 - 4603 (2021/01/18)

By using Rh–H catalysis, we couple α-nitroesters and alkynes to prepare α-amino-acid precursors. This atom-economical strategy generates two contiguous stereocenters, with high enantio- and diastereocontrol. In this transformation, the alkyne undergoes isomerization to generate a RhIII–π-allyl electrophile, which is trapped by an α-nitroester nucleophile. A subsequent reduction with In powder transforms the allylic α-nitroesters to the corresponding α,α-disubstituted α-amino esters.

Convenient synthesis of 4,5-unsubstituted 3-aroylisoxazoles from methyl aryl ketones and (vinylsulfonyl)benzene in water

Wang, Liang,Tao, Yu,Zhang, Nana,Li, Shubai

, (2021/01/11)

A convenient synthesis of 3-aroylisoxazoles from methyl ketones and (vinylsulfonyl)benzene in 2%TPGS-750-M/H2O has been developed. This reaction proceeds via tandem tert-butyl nitrite-promoted Csp3-H functionalization of methyl ketones, 1,3-dipolar cycloaddition and base-catalyzed aromatization, providing the corresponding products in moderate to good yields.

Metal-free oxidative nitration of α-carbon of carbonyls leads to one-pot synthesis of thiohydroximic acids from acetophenones

Dighe, Shashikant U.,Mukhopadhyay, Sushobhan,Priyanka, Kumari,Batra, Sanjay

supporting information, p. 4190 - 4193 (2016/09/09)

A metal-free nitration of the α-C-H to carbonyl in propiophenones was achieved with I2/NaNO2 in the presence of an oxidant in dimethyl sulfoxide (DMSO) as the medium. Conversely under similar conditions, reaction of acetophenones produced thiohydroximic acids via a radical-based cascade event which involves oxidative nitration of the α-carbon to a carbonyl followed by Michael addition of the thiomethyl group from DMSO and subsequent rearrangement. Besides DMSO, the scope of the reaction encompasses other symmetrical and unsymmetrical dialkylsulfoxides.

Asymmetric Michael addition of α-nitro-ketones using catalytic peptides

Linton, Brian R.,Reutershan, Michael H.,Aderman, Christopher M.,Richardson, Elizabeth A.,Brownell, Kristen R.,Ashley, Charles W.,Evans, Catherine A.,Miller, Scott J.

, p. 1993 - 1997 (2007/10/03)

Peptide-based catalysts have been developed that promote the asymmetric Michael addition of nitroalkanes. The most effective peptides contain a β-turn structural element as well as a basic histidine and an arylsulfonamide-protected arginine. Excellent yields with enantioselectivities of up to 74% ee have been observed.

Chromate oxidation of α-nitro alcohols to α-nitro ketones: Significant improvements to a classic method

Elmaaty, Tarek Abou,Castle, Lyle W.

, p. 1458 - 1461 (2007/10/03)

A series of eight alkyl and aryl α-nitro ketones were prepared by the potassium dichromate oxidation of the corresponding nitro alcohols. Short reaction times allowed for the easy isolation of pure nitro ketones that are devoid of starting materials and/o

α-nitration of ketones via enol silyl ethers. Radical cations as reactive intermediates in thermal and photochemical processes

Rathore, Rajendra,Kochi, Jay K.

, p. 627 - 639 (2007/10/03)

Highly colored (red) solutions of various enol silyl ethers and tetranitromethane (TNM) are readily bleached to afford good yields of α-nitro ketones in the dark at room temperature or below. Spectral analysis show the red colors to be associated with the intermolecular 1:1 electron donor-acceptor (EDA) complexes between the enol silyl ether and TNM. The formation of similar vividly colored EDA complexes with other electron acceptors (such as chloranil, tetracyanobenzene, tetracyanoquinodimethane, etc.) readily establish enol silyl ethers to be excellent electron donors. The deliberate irradiation of the diagnostic (red) charge-transfer absorption bands of the EDA complexes of enol silyl ethers and TNM at -40 °C affords directly the same α-nitro ketones, under conditions in which the thermal reaction is too slow to compete. A common pathway is discussed in which the electron transfer from the enol silyl ether (ESE) to TNM results in the radical ion triad [ESE?+, NO2?, C(NO2)3-]. A subsequent fast homolytic coupling of the cation radical of the enol silyl ether with NO2? leads to the α-nitro ketones. The use of time-resolved spectroscopy and the disparate behavior of theisomeric enol silyl ethers of α- and β-tetralones as well as of 2-methylcyclohexanone strongly support cation radicals (ESE?+) as the critical intermediate in thermal and photoinduced electron-transfer as described in Schemes 1 and 2, respectively.

A novel one pot synthesis of α-nitroketones from olefins using trimethylsilylnitrate-chromium trioxide reagent system

Reddy, M. Venkat Ram,Kumareswaran,Vankar, Yashwant D.

, p. 7149 - 7152 (2007/10/02)

A variety of α-nitroketones have been obtained from the corresponding olefins in good yields upon reaction with trimethylsilylnitrate-chromium trioxide reagent system.

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