59540-80-6

Basic information

• Product Name: 4-Heptanone, 1-phenyl-
• CAS NO: 59540-80-6
• Molecular Formula: C13H18O
• Molecular Weight: 190.285
• Mol File: 59540-80-6.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: 4-Heptanone, 1-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 4-Heptanone, 1-phenyl-(59540-80-6)
• EPA Substance Registry System: 4-Heptanone, 1-phenyl-(59540-80-6)

Safety Data

• Hazardous Substances Data: 59540-80-6(Hazardous Substances Data)

Upstream product

• 141-75-3 butyryl chloride 
• 2687-12-9 cinnamyl chloride 
• 4119-41-9 1-iodo-3-phenylpropan 
• 1462-75-5 3-phenylpropylmagnesium bromide 
• 18643-50-0 1-pentynyl lithium 
• 100-42-5 styrene 
• 560095-48-9 (1-hexen-3-yl)pentamethyl phosphoric triamide 
• 560095-45-6 C₁₀H₂₄N₃OP 
• 560095-42-3 (1-hexen-3-yl)amidophosphoric dichloride 
• 4181-11-7 3-hex-1-enylamine 
• 560095-63-8 (1-phenyl-3-hepten-4-yl)pentamethyl phosphoric triamide 
• 300-57-2 allylbenzene 
• 6117-91-5 (E/Z)-2-buten-1-ol 
• 144741-88-8 1-phenylheptan-4-ol 

Relevant articles and documents

A General Approach to Intermolecular Olefin Hydroacylation through Light-Induced HAT Initiation: An Efficient Synthesis of Long-Chain Aliphatic Ketones and Functionalized Fatty Acids

Herein, an operationally simple, environmentally benign and effective method for intermolecular radical hydroacylation of unactivated substrates by employing photo-induced hydrogen atom transfer (HAT) initiation is described. The use of commercially available and inexpensive photoinitiators (Ph2CO and NHPI) makes the process attractive. The olefin hydroacylation protocol applies to a wide array of substrates bearing numerous functional groups and many complex structural units. The reaction proves to be scalable (up to 5 g). Different functionalized fatty acids, petrochemicals and naturally occurring alkanes can be synthesized with this protocol. A radical chain mechanism is implicated in the process.

SiO2-TBD as new heterogeneous catalyst for the nef conversion of secondary nitroalkanes under neat conditions

Treatment of secondary nitroalkanes with neat silica-supported 1,5,7-triazabicyclo[4.4.0]dec-5-ene (TBD), at room temperature, allows the direct conversion of the secondary nitro groups to the corresponding keto carbonyls. Georg Thieme Verlag Stuttgart.

Unprecedented, selective Nef reaction of secondary nitroalkanes promoted by DBU under basic homogeneous conditions

Secondary nitrocompounds can be converted into the corresponding ketones under basic conditions using DBU in acetonitrile. Primary nitroalkanes are unaffected by these conditions. Elsevier Science Ltd. All rights reserved.