59584-27-9Relevant articles and documents
Transformation of carbonates into sulfones at the benzylic position via palladium-catalyzed benzylic substitution
Kuwano, Ryoichi,Kondo, Yutaka,Shirahama, Tsuyoshi
, p. 2973 - 2975 (2007/10/03)
(Chemical Equation Presented) The nucleophilic substitution of benzylic carbonates with sodium arenesulfinates was catalyzed by the palladium complex generated in situ from [Pd(η3-C3H5)Cl] 2 and DPEphos [bis(2-diphenylphosphinophenyl)ether]. The catalytic reaction proceeded in DMSO at 80°C and gave a variety of benzylic sulfones in high yields.
Synthesis and Spetral Studies of Some Alkyl benzoate Derivatives. 3.
El-Bardan, Ali A.,Hamed, Ezzat A.,Saad, Esmat F.
, p. 133 - 134 (2007/10/02)
The synthesis, IR spectra, and proton NMR spectra of some alkyl benzoate derivatives are reported.
Synthesis and antifolate properties of 10-alkyl-8,10-dideazaminopterins
DeGraw,Christie,Brown,Kelly,Kisliuk,Gaumont,Sirotnak
, p. 376 - 380 (2007/10/02)
The synthesis of 10-alkyl analogues of the potent antitumor agent 8,10-dideazaminopterin is described. Alkylation of appropriate α-alkyl homoterephthalate esters with 2,4-diamino-6-(bromomethyl)-8-deazapteridine afforded 10-alkyl-10-carboxy-4-amino-4-deox