59679-95-7Relevant articles and documents
Ohta,Tetsukawa
, p. 849 (1978)
Reaction of Hydrogen Halides with 1,2-Hexadecanediol
Ahmad, M. S.,Khan, Mushfiquddin,Osman, S. M.
, p. 1001 - 1002 (2007/10/02)
Reaction of 1,2-hexadecanediol (I) with hydrochloric acid in the presence of acetic anhydride gives a mixture of 2-acetoxy-1-hydroxyhexadecane (III) and 1,3-hexadecanediol (V).However, a similar treatment of I with hydroiodic acid in the presence of acetic anhydride furnishes 1-iodo-2-acetoxyhexadecane (VII), 1,2-diacetoxyhexadecane (VI) and 1-acetoxy-2-hydroxyhexadecane (IV).Structures of the products III, IV, V, VI and VII have been established on the basis of elemental analyses, spectral data and chemical evidence.