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7320-37-8

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7320-37-8 Usage

General Description

White waxy solid or clear colorless liquid. Faint pleasant odor.

Air & Water Reactions

Moisture sensitive. Insoluble in water.

Reactivity Profile

The neat compound, 1,2-EPOXYHEXADECANE, is sensitive to prolonged exposure to heat. 1,2-EPOXYHEXADECANE is also moisture sensitive. 1,2-EPOXYHEXADECANE reacts with inorganic acids, thiosulfate, carboxylic acids, hydrogen cyanide, water, amines, aldehydes, alcohols, and caustics. 1,2-EPOXYHEXADECANE will also react with amino, hydroxyl and carboxyl groups.

Fire Hazard

Flash point data are not available for 1,2-EPOXYHEXADECANE, but 1,2-EPOXYHEXADECANE is probably combustible.

Flammability and Explosibility

Nonflammable

Safety Profile

Questionable carcinogen with experimental tumorigenic data. Mutation data reported. When heated to decomposition it emits acrid smoke and fumes.

Check Digit Verification of cas no

The CAS Registry Mumber 7320-37-8 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 7,3,2 and 0 respectively; the second part has 2 digits, 3 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 7320-37:
(6*7)+(5*3)+(4*2)+(3*0)+(2*3)+(1*7)=78
78 % 10 = 8
So 7320-37-8 is a valid CAS Registry Number.
InChI:InChI=1/C16H32O/c1-2-3-4-5-6-7-8-9-10-11-12-13-14-16-15-17-16/h16H,2-15H2,1H3

7320-37-8 Well-known Company Product Price

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  • Aldrich

  • (260215)  1,2-Epoxyhexadecane  technical grade, 85%

  • 7320-37-8

  • 260215-100ML

  • 1,111.50CNY

  • Detail

7320-37-8SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name 1,2-Epoxyhexadecane

1.2 Other means of identification

Product number -
Other names 1,2-Epoxyhexadecane

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:7320-37-8 SDS

7320-37-8Relevant articles and documents

Proton Switch in the Secondary Coordination Sphere to Control Catalytic Events at the Metal Center: Biomimetic Oxo Transfer Chemistry of Nickel Amidate Complex

Kim, Soohyung,Jeong, Ha Young,Kim, Seonghan,Kim, Hongsik,Lee, Sojeong,Cho, Jaeheung,Kim, Cheal,Lee, Dongwhan

supporting information, p. 4700 - 4708 (2021/02/12)

High-valent metal-oxo species are key intermediates for the oxygen atom transfer step in the catalytic cycles of many metalloenzymes. While the redox-active metal centers of such enzymes are typically supported by anionic amino acid side chains or porphyrin rings, peptide backbones might function as strong electron-donating ligands to stabilize high oxidation states. To test the feasibility of this idea in synthetic settings, we have prepared a nickel(II) complex of new amido multidentate ligand. The mononuclear nickel complex of this N5 ligand catalyzes epoxidation reactions of a wide range of olefins by using mCPBA as a terminal oxidant. Notably, a remarkably high catalytic efficiency and selectivity were observed for terminal olefin substrates. We found that protonation of the secondary coordination sphere serves as the entry point to the catalytic cycle, in which high-valent nickel species is subsequently formed to carry out oxo-transfer reactions. A conceptually parallel process might allow metalloenzymes to control the catalytic cycle in the primary coordination sphere by using proton switch in the secondary coordination sphere.

Synthesis of (2 S,3 R,5 R)-2-Azido-3,5-dihydroxynonadecane Sphingolipid Analogue

Pemha, René,Pegnyemb, Dieudonné Emmanuel,Mosset, Paul

, p. 2572 - 2578 (2020/11/03)

A concise and highly efficient synthesis of an enigmol analogue has been achieved. The synthetic strategy features Jacobsen's hydrolytic kinetic resolution (HKR) and epoxide opening by alkynyl boranes as the key steps.

Catalyst-Controlled Multicomponent Aziridination of Chiral Aldehydes

Mukherjee, Munmun,Zhou, Yubai,Dai, Yijing,Gupta, AniL K.,Pulgam, V. Reddy,Staples, Richard J.,Wulff, William D.

supporting information, p. 2552 - 2556 (2017/03/06)

A highly diastereoselective and enantioselective method for the multicomponent aziridination of chiral aldehydes has been developed with BOROX catalysts of the VANOL (3,3′-diphenyl-2,2′-bi-1-naphthol) and VAPOL (2,2′-diphenyl-(4-biphenanthrol)) ligands. Very high to perfect catalyst control is observed with most all substrates examined including aldehydes with chiral centers in the α- and β-positions. High catalyst control was also observed for a number of chiral heterocyclic aldehydes allowing for the preparation of epoxy aziridines, bis(aziridines) and ethylene diaziridines. Application of this reaction in the synthesis of β3-homo-d-alloisoleucine and β3-homo-l-isoleucine is reported.

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