59985-72-7Relevant academic research and scientific papers
2-(3-Lithiopropyl)- and 2-(3-lithiopropyl)-2-methyl-1,3-dioxolane: New masked lithium bishomoenolates in the synthesis of bifunctionalized compounds
Ramon, Diego J.,Yus, Miguel
, p. 3763 - 3766 (1990)
2-(3-Lithiopropyl)- and 2-(3-lithiopropyl)-2-methyl-1,3-dioxolane (2) are prepaned by lithiation of the corresponding chlorinated precursors with lithium naphthalenide at -78°C. The reaction of these masked bishomoenolates with different electrophiles yie
Masked Lithium Bishomoenolates: Useful Intermediates in Organic Synthesis
Ramon, Diego J.,Yus, Miguel
, p. 3825 - 3831 (2007/10/02)
The lithiation of the chloro ketals 9 with lithium naphthalenide at -78 deg C led to the corresponding masked lithium bishomoenolates 4, which are stable species under these conditions and react with different electrophilic reagents (H2O, D2O, i-PrCOH, Ph
