60068-18-0

Basic information

• Product Name: 1-Trimethylsilanyloxy-4-(1-trimethylsilanyloxy-vinyl)-benzene
• Synonyms: 1-Trimethylsilanyloxy-4-(1-trimethylsilanyloxy-vinyl)-benzene
• CAS NO: 60068-18-0
• Molecular Weight: 280.514
• Mol File: 60068-18-0.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 1-Trimethylsilanyloxy-4-(1-trimethylsilanyloxy-vinyl)-benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Trimethylsilanyloxy-4-(1-trimethylsilanyloxy-vinyl)-benzene(60068-18-0)
• EPA Substance Registry System: 1-Trimethylsilanyloxy-4-(1-trimethylsilanyloxy-vinyl)-benzene(60068-18-0)

Safety Data

• Hazardous Substances Data: 60068-18-0(Hazardous Substances Data)

Upstream product

• 24589-78-4 N-methyl-N-trimethylsilyl-2,2,2-trifluoroacetamide 
• 99-93-4 4-Hydroxyacetophenone 
• 75-77-4 chloro-trimethyl-silane 
• 18803-29-7 4'-(trimethylsilyloxy)acetophenone 

Downstream Products

• 2491-32-9 1-(4-Hydroxyphenyl)-2-phenylethanone 
• 60068-22-6 1-Trimethylsilanyloxy-4-(1-trimethylsilanyloxy-cyclopropyl)-benzene 

Relevant articles and documents

Versatile and base-free copper-catalyzed α-arylations of aromatic ketones using diaryliodonium salts

A ligand and base-free copper catalyzed synthetic method for the efficient α-arylation of aromatic ketones is described. In order to avoid strong bases, ketone-derived silyl enol ethers were employed. Their reaction with diaryliodonium salts as aryl source provided the intermolecular C–C coupling displaying good functional group tolerance and requiring low catalyst loading.

PHENOLIC COMPOUNDS FROM ROOTS OF URTICA DIOICA

Root extracts from Urtica dioica were separated into several classes of compounds by extraction with organic solvents at different pH values.The phenolic fraction was analysed by GC-MS after trimethylsilylation.This procedure allowed the identification of 18 phenolic compounds as well as the detection of eight lignans.The occurrence of some of these substances in this plant was previously unknown.