6007-83-6Relevant academic research and scientific papers
Solution-processed, molecular photovoltaics that exploit hole transfer from non-fullerene, n-type materials
Douglas, Jessica D.,Chen, Mark S.,Niskala, Jeremy R.,Lee, Olivia P.,Yiu, Alan T.,Young, Eric P.,Fréchet, Jean M.J.
, p. 4313 - 4319 (2014)
Solution-processed organic photovoltaic devices containing p-type and non-fullerene n-type small molecules obtain power conversion efficiencies as high as 2.4%. The optoelectronic properties of the n-type material BT(TTI-n12)2 allow these devic
Physical Properties in Thin Films of a Thienoimide End-capped Compound
Tachibana,Toda,Azumi
, p. 82 - 88 (2019)
We have synthesized a new compound of a benzothiadiazole central core coupled to terminal thienoimide (TI) via vinyl linker, namely, C8-TI-BT. We investigated physical properties of vacuum-deposited and spin-coated thin films of C8-TI-BT. Optical properties of C8-TI-BT were different between thin films fabricated by vacuum deposition and spin-coating method. The vacuum-deposited films become more ordered structures by heat treatment. The thin-film transistor (TFT) shows ambipolar semiconducting behavior. We further demonstrated characteristics of electroluminescence (EL) device with the spin-coated C8-TI-BT films.
BENZOBIS-(THIADIAZOLE) DERIVATIVE, INK CONTAINING THE SAME, AND ORGANIC ELECTRONICS DEVICE USING THE SAME
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Paragraph 0257; 0263; 0264; 0265; 0266, (2016/10/08)
The object of the present invention is to provide a benzobis-(thiadiazole) derivative which has excellent electron mobility (field-effect mobility) and excellent stability in the atmosphere. The present invention relates to a benzobis-(thiadiazole) derivative which has a cyclic imide structure with condensed aromatic ring in its molecule shown in the formula (1) or (2): (In the formula, R, A and Z represent specific groups.)
ORGANIC SEMICONDUCTOR MATERIAL
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Page/Page column 22, (2012/12/13)
The present invention relates to a novel compounds useful as organic semiconductor material, and semiconductor devices containing said organic semiconductor material.
Thienopyrrolyl dione end-capped oligothiophene ambipolar semiconductors for thin film- and light emitting transistors
Melucci, Manuela,Zambianchi, Massimo,Favaretto, Laura,Gazzano, Massimo,Zanelli, Alberto,Monari, Magda,Capelli, Raffaella,Troisi, Stefano,Toffanin, Stefano,Muccini, Michele
supporting information; experimental part, p. 11840 - 11842 (2011/12/02)
The design, synthesis and structure-property investigation of a new thienopyrrolyl dione substituted oligothiophene material showing reduced band gap energy, low lying LUMO energy level and ambipolar semiconducting behaviour is described.
Thermolysis of Thiophenedicarboxylic Acid Anhydrides as a Route to Five-Membered Hetarynes
Reinecke, Manfred G.,Newsom, James G.,Chen, Lao-Jer
, p. 2760 - 2769 (2007/10/02)
Flow vacuum thermolysis (FVT) of the anhydrides of thiophene-2,3- (5) and -3,4-dicarboxylic acid (6) and of thianaphthene-2,3-dicarboxylic acid (7) in the presence of thiophene, 1,3-cyclohexadiene, or benzene gave thianthrene (15a), presumably by aromatization of an intermadiate Diels-Alder adduct of the diene traps and the aryne 2,3-didehydrothiophene (8).A similar rationale explains the formation of dibenzothiophene from 7 and thiophene, the four monomethylthianaphthenes 22-25 from 5 and cyclopentadiene, 5,6-dimethylthianaphthene (15f) from 5 and 2,3-dimethylbutadiene, and a mixture of hydroxythianaphthenes (15d) from 5 and furan.The latter reaction also produces a mixture of isomeric cyclopentanothiophenes (19) which probably arise by decarbonylation of 15d.An FVT reaction of 5 with propyne as the trap gave a mixture of allenyl-(28) and propynylthiophenes 29 which probably arise by an ene reaction of the trap and the aryne 8.Decomposition of the anhydrides 5 and 6 in molten anthracene led only to Friedel-Crafts products such as thienylanthracenes 33 and quinones 34 from 5 and 39 and 40 from 6.The diene reactivity of thiophene 13a in the gas phase was demonstrated by the formation of naphthalene from its reaction with benzyne generated from the thermolysis of indanetrione and by the formation of indene from 13a plus cyclopentadiene.Possible, but improbable, interpretations of the FVT results without invoking a five-membered hetaryne intermediate are considered.
