60127-34-6

Basic information

• Product Name: 4-methoxyphenyl 4-methoxybenzoate
• Synonyms: 4-methoxyphenyl 4-methoxybenzoate
• CAS NO: 60127-34-6
• Molecular Formula: C₁₅H₁₄O₄
• Molecular Weight: 258.26926
• Mol File: 60127-34-6.mol
• Article Data: 25

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 4-methoxyphenyl 4-methoxybenzoate(CAS DataBase Reference)
• NIST Chemistry Reference: 4-methoxyphenyl 4-methoxybenzoate(60127-34-6)
• EPA Substance Registry System: 4-methoxyphenyl 4-methoxybenzoate(60127-34-6)

Safety Data

• Hazardous Substances Data: 60127-34-6(Hazardous Substances Data)

Upstream product

• 10019-24-6 1,1,2,2-tetrakis(4-methoxyphenyl)ethene 
• 5720-07-0 4-methoxyphenylboronic acid 
• 123-11-5 4-methoxy-benzaldehyde 
• 696-62-8 para-iodoanisole 
• 104-88-1 4-chlorobenzaldehyde 
• 150-76-5 4-methoxy-phenol 
• 456-22-4 4-Fluorobenzoic acid 
• 100-09-4 4-methoxybenzoic acid 
• 105-13-5 4-Methoxybenzyl alcohol 
• 3400-22-4 4-methoxy-N-methylbenzamide 
• 3424-93-9 4-methoxyphenylacetamide 
• 19820-47-4 4-methoxyphenyl 2,2-dimethylpropionate 
• 201230-82-2 carbon monoxide 
• 4525-64-8 4-methoxyphenyl formate 

Downstream Products

• 80427-36-7 (5-Hydroxy-2-methoxy-phenyl)-(4-methoxy-phenyl)-methanone 
• 80427-30-1 4-Methoxy-benzoic acid 4-methoxy-3-(4-methoxy-benzoyl)-phenyl ester 
• 16762-04-2 2-hydroxy-4',5-dimethoxybenzophenone 

Relevant articles and documents

Decarboxylative Hydroxylation of Benzoic Acids

Herein, we report the first decarboxylative hydroxylation to synthesize phenols from benzoic acids at 35 °C via photoinduced ligand-to-metal charge transfer (LMCT)-enabled radical decarboxylative carbometalation. The aromatic decarboxylative hydroxylation is synthetically promising due to its mild conditions, broad substrate scope, and late-stage applications.

Cobalt-Catalyzed Esterification of Amides

The first cobalt-catalyzed amide activation of N-Boc-amides, and their conversion into esters, is reported here. This new methodology presents a very practical process that does not require an inert atmosphere, uses an inexpensive cobalt catalyst, and proceeds under mild reaction conditions. This catalytic system has a broad substrate scope and has been shown to be highly efficient, with catalyst loadings as low as 1 mol %.

Direct synthesis of symmetrical azines from alcohols and hydrazine catalyzed by a ruthenium pincer complex: Effect of hydrogen bonding

Azines (2,3-diazabuta-1,3-dienes) are a widely used class of compounds with conjugated CN double bonds. Herein, we present a direct synthesis of azines from alcohols and hydrazine hydrate. The reaction, catalyzed by a ruthenium pincer complex, evolves dihydrogen and can be run in a base-free version The deh dro enative cou lin of benz lic and aliphatic alcohols led to good conversions and yields. Spectroscopic evidence for a hydrazine-coordinated dearomatized ruthenium pincer complex was obtained. Isolation of a supramolecular crystalline compound provided evidence for the important role of hydrogen bonding networks under the reaction conditions.