602-77-7

Basic information

• Product Name: 1,5-DIBROMOANTHRAQUINONE
• Synonyms: 1,5-DIBROMOANTHRAQUINONE;DIBROMOANTHRAQUINONE;1,5-Dibromo-9,10-anthraquinone;1,5-dibromo-9,10-Anthracenedione;1,5-Dibromoanthracene-9,10-dione
• CAS NO: 602-77-7
• Molecular Formula: C₁₄H₆Br₂O₂
• Molecular Weight: 366
• Product Categories: Anthraquinones;Chloroanthraquine, etc.;Highly Purified Reagents;Other Categories;Refined Products by Sublimation
• Mol File: 602-77-7.mol
• Article Data: 9

Chemical Properties

• Melting Point: 292 °C
• Boiling Point: 491.8°C at 760 mmHg
• Flash Point: 172.2°C
• Appearance: /
• Density: 1.911g/cm³
• Vapor Pressure: 8.12E-10mmHg at 25°C
• Refractive Index: 1.7
• CAS DataBase Reference: 1,5-DIBROMOANTHRAQUINONE(CAS DataBase Reference)
• NIST Chemistry Reference: 1,5-DIBROMOANTHRAQUINONE(602-77-7)
• EPA Substance Registry System: 1,5-DIBROMOANTHRAQUINONE(602-77-7)

Safety Data

• Hazardous Substances Data: 602-77-7(Hazardous Substances Data)

Usage

General Description

1,5-DIBROMOANTHRAQUINONE is a chemical compound with the molecular formula C14H6Br2O2. It is a derivative of anthraquinone, a naturally occurring organic compound found in various plants. 1,5-DIBROMOANTHRAQUINONE is a yellow solid that is insoluble in water but soluble in organic solvents. It is commonly used as a chemical intermediate in the synthesis of dyes, pigments, and pharmaceuticals. In addition, it is also used as a corrosion inhibitor and as a reagent in organic chemical reactions. However, it should be handled with caution as it is toxic and may cause skin and eye irritation.

InChI:InChI=1/C14H6Br2O2/c15-9-5-1-3-7-11(9)14(18)8-4-2-6-10(16)12(8)13(7)17/h1-6H

Upstream product

• 82-46-2 1,5-Dichloroanthraquinone 
• 129-44-2 1,5-diaminoanthraquinone 
• 84-65-1 9,10-phenanthrenequinone 
• 82-49-5 1-anthraquinonesulfonic acid 
• 82-48-4 1,8-anthraquinonedisulphonic acid 
• 117-14-6 1,5-anthraquinone disulfonate 
• 7732-18-5 water 
• 7726-95-6 bromine 
• 86119-84-8 phosphoric acid 
• 98-95-3 nitrobenzene 
• 853-35-0 sodium anthraquinone-1,5-disulphonate 

Downstream Products

• 2987-66-8 1,5-dimethylaminoanthraquinone 
• 117-12-4 1,5-dihydroxyanthraquinone 
• 632-83-7 1-Bromoanthraquinone 
• 1548688-66-9 [2,6-diisopropyl-4-(5-bromoanthraquinon-1-yl)phenyl]bis(2,4,6-triisopropylphenyl)phosphine 
• 1548688-58-9 1,5-bis[3,5-diisopropyl-4-{bis(2,4,6-triisopropylphenyl)phosphino}phenyl]anthraquinone 
• 3278-82-8 1,5-dibromoanthraquinone 
• 4981-66-2 9,10-Dihydroxyanthracene 

Relevant articles and documents

Modular Approach to the Synthesis of Two-Dimensional Angular Fused Acenes

Herein, we present a modular approach to pristine angularly fused planar acenes. The approach includes the Pd-catalyzed fusion of several building blocks and implements a dehydrative ?-extension (DPEX) reaction as a key step enabling facile access to diverse two-dimensional acenes. The scope was demonstrated on nine examples with up to quantitative yield.

Ruthenium-catalyzed C-H oxygenation of quinones by weak O-coordination for potent trypanocidal agents

Ruthenium-catalysis enabled the C-5 selective C-H oxygenation of naphthoquinones, and also sets the stage for the site-selective introduction of a hydroxyl group into anthraquinones. A-ring modified naphthoquinoidal compounds represent an important class of bioactive quinones for which the present study encompasses the first C-H oxygenation strategy by weak O-coordination.

Synthesis and properties of sterically crowded triarylphosphines bearing anthra- and naphtho-quinones, and their oligomers

Sterically crowded triarylphosphines bearing anthraquinones were synthesized by SuzukieMiyaura coupling of arylboronic acids derived from (bromoaryl)phosphines with haloanthraquinones. The anthraquinone bearing the two triarylphosphine moieties at the 2,6