60210-93-7

Upstream product

• 2568-17-4 bicyclo[3.3.1]nonan-2-one 
• 60211-04-3 Methanesulfonic acid (1S,2R,5R,9R)-2-hydroxy-bicyclo[3.3.1]non-9-yl ester 
• 371113-36-9 2-(2-cyclohex-2-enylethyl)-1,3-dioxolane 
• 15745-87-6 3-cyclohex-2-en-1-ylpropan-1-ol 
• 10407-33-7 methyl 3-(2-oxocyclohexyl)propionate 
• 1521-51-3 rac-3-bromocyclohexene 
• 110-83-8 cyclohexene 
• 73974-93-3 3-(2-oxocyclohexyl)propyl acetate 
• 62885-64-7 3-(1,4-dioxaspiro[4.5]dec-6-yl)propionic acid methyl ester 
• 62547-87-9 3-(1,4-dioxaspiro[4,5]dec-6-yl)propan-1-ol 
• 929049-83-2 3-(2-{2-[(4-methylphenyl)sulfonyl]hydrazono}cyclohexyl)propyl acetate 
• 929049-82-1 3-(1,4-dioxaspiro[4,5]dec-6-yl)propyl acetate 
• 766-03-0 3-vinylcyclohexene 
• 201230-82-2 carbon monoxide 

Downstream Products

• 1888-90-0 3-methylene-cyclohexene 
• 1124-63-6 3-cyclohexylpropan-1-ol 
• 60211-05-4 (E)-5-Cyclohex-2-enyl-2-cyclohex-2-enylmethyl-pent-2-enal 
• 406674-31-5 3-(2-cyclohexen-1-yl)propanal O-benzyl oxime 
• 60211-19-0 spiro[3.5]nonan-1-ol 
• 4430-31-3 (+/-)-(4aR,8aR)-octahydro-2H-chromen-2-one 
• 76837-82-6 (+/-)-3-(cyclohex-2-enyl)propanoic acid 

Relevant academic research and scientific papers

Stereocontrolled synthesis of substituted bicyclic ethers through oxy-Favorskii rearrangement: Total synthesis of (±)-communiol e

The potential of the oxy-Favorskii rearrangement to form branched cis-fused bicyclic ethers was explored. Both tertiary and quaternary centers were constructed in highly stereospecific manners. Methanol and primary amines were effective nucleophiles for the rearrangement. The total synthesis of (±)-communiol E was achieved based on this method.

Preparation of sixteen 3-hydroxy-4- and 7-hydroxy-1-hydrindanones and 3-hydroxy-4- and 8-hydroxy-1-hydroazulenones

3-Hydroxyoctahydro-4H-inden-4-ones and 7-hydroxyoctahydro-1H-inden-1-ones (1, 2 and 3, 4, respectively), as well as the homologous 3-hydroxyoctahydro- 4(1H)-azulenones (5, 6) and 8-hydroxyoctahydro-1(2H)-azulenones (7, 8), were prepared diastereoselective

Stereoselective electrophile-induced mono- and bis-cyclisation-fragmentation reactions of alkenyl oxime O-allyl and O-benzyl ethers. Synthesis of dihydropinidine

Phenylseleny bromide-induced cyclisation of γ- and δ-unsaturated aldoxime and ketoxime O-allyl and O-benzyl ethers is followed by a slow fragmentation of the resultant oxyiminium ions furnishing cyclic iminium salts which are readily reduced to pyrrolidines, piperidines or tetrahydroisoquinolines by sodium borohydride; dialkenyl oximes yield indolizidines and quinolizidines by an analogous sequence terminating in a mercury(II)-induced cyclisation.

X=Y-ZH Systems as potential 1,3-dipoles. Part 52: Fused-ring forming electrophile induced oxime→nitrone→cycloaddition cascades

Electrophile induced cyclisation of oximes onto endocyclic alkenes and exo-methylene cycloalkanes occurs stereo- and regio-specifically generating cis-fused bicyclic nitrones in good yield. Subsequent facially selective cycloaddition with N-methylmaleimid

A further breakthrough in biphasic, rhodium-catalyzed hydroformylation: The use of per(2,6-di-O-methyl)-β-cyclodextrin as inverse phase transfer catalyst

Solvent free biphasic hydroformylation of various water-insoluble terminal olefins can be achieved in high yields and selectivities by using a water-soluble rhodium/triphenylphosphine trisulfonate catalyst and per(2,6-di-o-methyl)-β-cyclodextrin as inverse phase transfer catalyst. The catalytic activities were up to ten times higher than those observed without per(2,6-di-o-methyl)-β-cyclodextrin.