60469-89-8Relevant academic research and scientific papers
Synthesis of Halogenated Anilines by Treatment of N, N-Dialkylaniline N-Oxides with Thionyl Halides
Reed, Hayley,Paul, Tyler R.,Chain, William J.
, p. 11359 - 11368 (2018/08/06)
The special reactivity of N,N-dialkylaniline N-oxides allows practical and convenient access to electron-rich aryl halides. A complementary pair of reaction protocols allow for the selective para-bromination or ortho-chlorination of N,N-dialkylanilines in up to 69% isolated yield. The generation of a diverse array of halogenated anilines is made possible by a temporary oxidation level increase of N,N-dialkylanilines to the corresponding N,N-dialkylaniline N-oxides and the excision of the resultant weak N-O bond via treatment with thionyl bromide or thionyl chloride at low temperature.
New Bis(benzene-1,2-dithiolato)Ni(II) Complexes Having Intense Near-Infrared Absorptions
Tabushi, Iwao,Yamamura, Kazuo,Nonoguchi, Hiroshi
, p. 1373 - 1376 (2007/10/02)
New bis(benzene-1,2-thiolato)Ni(II)*n-Bu4N having one or two N,N-dimethylamino substituent(s) were prepared.The main characteristic in their electronic absorptions was the intense near-infrared absorption band with a maximum of intensity at 990-1163 nm.
