6084-15-7

Basic information

• Product Name: 2-iodo-1-phenylpropan-1-one
• CAS NO: 6084-15-7
• Molecular Formula: C₉H₉IO
• Molecular Weight: 260.0716
• Mol File: 6084-15-7.mol
• Article Data: 28

Chemical Properties

• Boiling Point: 286.7°C at 760 mmHg
• Flash Point: 127.2°C
• Density: 1.659g/cm³
• Vapor Pressure: 0.00259mmHg at 25°C
• Refractive Index: 1.603
• CAS DataBase Reference: 2-iodo-1-phenylpropan-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: 2-iodo-1-phenylpropan-1-one(6084-15-7)
• EPA Substance Registry System: 2-iodo-1-phenylpropan-1-one(6084-15-7)

Safety Data

• Hazardous Substances Data: 6084-15-7(Hazardous Substances Data)

Upstream product

• 41518-22-3 3-iodopropionyl chloride 
• 71-43-2 benzene 
• 39623-95-5 1-phenylprop-1-enyl acetate 
• 14236-72-7 2-methylsulfanyl-1-phenyl-propan-1-one 
• 5667-47-0 phenacyldimethylsulfonium bromide 
• 25310-92-3 propiophenone dimethyl acetal 
• 93-55-0 1-phenyl-propan-1-one 
• 149-73-5 trimethyl orthoformate 
• 637-50-3 1-phenylpropene 
• 87456-64-2 α-tosyloxypropiophenone 
• 67-56-1 methanol 
• 93-54-9 1-Phenyl-1-propanol 
• 4393-06-0 1-Phenyl-2-propen-1-ol 
• 6540-76-7 iodine monoacetate 

Downstream Products

• 3617-18-3 2‐(3‐oxo‐3‐phenylpropyl)isoindoline‐1,3‐dione 
• 93-55-0 1-phenyl-propan-1-one 
• 105590-47-4 3-hydroxy-2-methyl-3-(4-nitrophenyl)-1-phenylpropan-1-one 
• 61878-73-7 3-hydroxy-2-methyl-1,3-diphenyl-propan-1-one 
• 79314-55-9 3-hydroxy-2-methyl-1-phenylpentan-1-one 
• 6084-17-9 2-chloro-1-phenylpropan-1-one 
• 135186-09-3 2-methyl-1-phenylcyclopropanol 
• 16735-22-1 3-hydroxy-2-methylpropiophenone 
• 71908-02-6 (2SR,3RS)-3-hydroxy-2-methyl-1,3-diphenylpropan-1-one 
• 71908-03-7 (2SR,3RS)-2-methyl-1,3-diphenyl-3-hydroxypropan-1-one 
• 86542-08-7 (2RS,3SR)-3-hydroxy-2-methyl-1-phenylbutan-1-one 
• 86542-09-8 (2RS,3RS)-3-hydroxy-2-methyl-1-phenylbutan-1-one 
• 5650-45-3 2-(morpholin-4-yl)-1-phenylpropan-1-one 

Relevant articles and documents

Iodine Monoacetate for Efficient Oxyiodinations of Alkenes and Alkynes

A novel and inexpensive, environmentally friendly method for the preparation of iodine monoacetate is presented using iodine and Oxone in acetic acid/acetic anhydride. The reagent is used in a highly efficient approach for the regio- and diastereoselective iodo-acetoxylation of alkenes and alkynes in a simple one-pot process.

Synthesis of α-Iodoketones from Allylic Alcohols through Aerobic Oxidative Iodination

An efficient method for the synthesis of α-iodoketones from allylic alcohols and elemental iodine is reported. We show in this paper that the isomerization of allylic alcohols catalyzed by iridium(III) complexes can be combined with an aerobic oxidative iodination protocol, resulting in a straightforward method for the synthesis of a wide range of α-iodoketones as single constitutional isomers and in high yields under mild reaction conditions. (Figure presented.).

2,2-Diiododimedone: A mild electrophilic iodinating agent for the selective synthesis of α-iodoketones from allylic alcohols

2,2-Diiodo-5,5-dimethylcyclohexane-1,3-dione is reported as a new electrophilic iodinating agent that selectively iodinates electron-rich aromatics. In contrast to other common electrophilic iodinating reagents, its mild nature allows it to be used for the selective synthesis of α-iodinated carbonyl compounds from allylic alcohols through a 1,3-hydrogen shift/iodination process catalyzed by iridium(iii) complexes.